Ferrocene and Transition Metal Bis(Dicarbollides) as Platform for Design of Rotatory Molecular Switches

Design of rotatory molecular switches based on extremely stable sandwich organometallic complexes ferrocene and bis(dicarbollide) complexes of transition metals is reviewed. The “on”–“off” switching in these systems can be controlled by various external stimuli such as change of the solution pH, int...

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Detalles Bibliográficos
Autor principal: Sivaev, Igor B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2017
Materias:
Review
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6149777/
https://www.ncbi.nlm.nih.gov/pubmed/29232924
http://dx.doi.org/10.3390/molecules22122201
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author Sivaev, Igor B.
author_facet Sivaev, Igor B.
author_sort Sivaev, Igor B.
collection PubMed
description Design of rotatory molecular switches based on extremely stable sandwich organometallic complexes ferrocene and bis(dicarbollide) complexes of transition metals is reviewed. The “on”–“off” switching in these systems can be controlled by various external stimuli such as change of the solution pH, interactions with coordinating species or redox reactions involving the central atom or substituents in the ligands.
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spelling pubmed-61497772018-11-13 Ferrocene and Transition Metal Bis(Dicarbollides) as Platform for Design of Rotatory Molecular Switches Sivaev, Igor B. Molecules Review Design of rotatory molecular switches based on extremely stable sandwich organometallic complexes ferrocene and bis(dicarbollide) complexes of transition metals is reviewed. The “on”–“off” switching in these systems can be controlled by various external stimuli such as change of the solution pH, interactions with coordinating species or redox reactions involving the central atom or substituents in the ligands. MDPI 2017-12-11 /pmc/articles/PMC6149777/ /pubmed/29232924 http://dx.doi.org/10.3390/molecules22122201 Text en © 2017 by the author. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Review
Sivaev, Igor B.
Ferrocene and Transition Metal Bis(Dicarbollides) as Platform for Design of Rotatory Molecular Switches
title Ferrocene and Transition Metal Bis(Dicarbollides) as Platform for Design of Rotatory Molecular Switches
title_full Ferrocene and Transition Metal Bis(Dicarbollides) as Platform for Design of Rotatory Molecular Switches
title_fullStr Ferrocene and Transition Metal Bis(Dicarbollides) as Platform for Design of Rotatory Molecular Switches
title_full_unstemmed Ferrocene and Transition Metal Bis(Dicarbollides) as Platform for Design of Rotatory Molecular Switches
title_short Ferrocene and Transition Metal Bis(Dicarbollides) as Platform for Design of Rotatory Molecular Switches
title_sort ferrocene and transition metal bis(dicarbollides) as platform for design of rotatory molecular switches
topic Review
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6149777/
https://www.ncbi.nlm.nih.gov/pubmed/29232924
http://dx.doi.org/10.3390/molecules22122201
work_keys_str_mv AT sivaevigorb ferroceneandtransitionmetalbisdicarbollidesasplatformfordesignofrotatorymolecularswitches

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