Acid-Induced Rearrangement of Epoxygermacranolides: Synthesis of Furanoheliangolides and Cadinanes from Nobilin

The acid-induced rearrangement of three epoxyderivatives of nobilin 1, the most abundant sesquiterpene lactone in Anthemis nobilis flowers, was investigated. From the 1,10-epoxyderivative 2, furanoheliangolide 5 was obtained, while the 4,5-epoxy group of 3 did not react. Conversely, when the 3-hydro...

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Detalles Bibliográficos
Autores principales: De Mieri, Maria, Smieško, Martin, Ismajili, Isidor, Kaiser, Marcel, Hamburger, Matthias
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2017
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6149915/
https://www.ncbi.nlm.nih.gov/pubmed/29258233
http://dx.doi.org/10.3390/molecules22122252

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6149915/
https://www.ncbi.nlm.nih.gov/pubmed/29258233
http://dx.doi.org/10.3390/molecules22122252

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