A Water Cluster Conduit in Crystal

The crystal structure of compound (1), [CuCl(phen)(H(2)NCH(2)COO)]∙4H(2)O, reveals an unusual hydrogen-bond water cluster aggregate T6(2)6(2). Four water molecules in (1) form an isolated water cluster, [(H(2)O)(14)](n), resembling a “phenanthro-[1,2]phenanthrene polymer structure shape” along the a...

Descripción completa

Detalles Bibliográficos
Autores principales: Jian, Fangfang, Liu, E, Xu, Jiao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2017
Materias:
Communication
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6150000/
https://www.ncbi.nlm.nih.gov/pubmed/29261117
http://dx.doi.org/10.3390/molecules22122278
Descripción
Sumario:The crystal structure of compound (1), [CuCl(phen)(H(2)NCH(2)COO)]∙4H(2)O, reveals an unusual hydrogen-bond water cluster aggregate T6(2)6(2). Four water molecules in (1) form an isolated water cluster, [(H(2)O)(14)](n), resembling a “phenanthro-[1,2]phenanthrene polymer structure shape” along the ac plane. The two face-face parallel [(H(2)O)(14)](n) planes are bridged by Cl atoms in [CuCl(phen) (H(2)NCH(2)COO)] with a strong O-H∙∙∙Cl hydrogen bond to form a water cluster conduit.

Ejemplares similares