A Water Cluster Conduit in Crystal

The crystal structure of compound (1), [CuCl(phen)(H(2)NCH(2)COO)]∙4H(2)O, reveals an unusual hydrogen-bond water cluster aggregate T6(2)6(2). Four water molecules in (1) form an isolated water cluster, [(H(2)O)(14)](n), resembling a “phenanthro-[1,2]phenanthrene polymer structure shape” along the a...

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Detalles Bibliográficos
Autores principales: Jian, Fangfang, Liu, E, Xu, Jiao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2017
Materias:
Communication
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6150000/
https://www.ncbi.nlm.nih.gov/pubmed/29261117
http://dx.doi.org/10.3390/molecules22122278
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author Jian, Fangfang
Liu, E
Xu, Jiao
author_facet Jian, Fangfang
Liu, E
Xu, Jiao
author_sort Jian, Fangfang
collection PubMed
description The crystal structure of compound (1), [CuCl(phen)(H(2)NCH(2)COO)]∙4H(2)O, reveals an unusual hydrogen-bond water cluster aggregate T6(2)6(2). Four water molecules in (1) form an isolated water cluster, [(H(2)O)(14)](n), resembling a “phenanthro-[1,2]phenanthrene polymer structure shape” along the ac plane. The two face-face parallel [(H(2)O)(14)](n) planes are bridged by Cl atoms in [CuCl(phen) (H(2)NCH(2)COO)] with a strong O-H∙∙∙Cl hydrogen bond to form a water cluster conduit.
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spelling pubmed-61500002018-11-13 A Water Cluster Conduit in Crystal Jian, Fangfang Liu, E Xu, Jiao Molecules Communication The crystal structure of compound (1), [CuCl(phen)(H(2)NCH(2)COO)]∙4H(2)O, reveals an unusual hydrogen-bond water cluster aggregate T6(2)6(2). Four water molecules in (1) form an isolated water cluster, [(H(2)O)(14)](n), resembling a “phenanthro-[1,2]phenanthrene polymer structure shape” along the ac plane. The two face-face parallel [(H(2)O)(14)](n) planes are bridged by Cl atoms in [CuCl(phen) (H(2)NCH(2)COO)] with a strong O-H∙∙∙Cl hydrogen bond to form a water cluster conduit. MDPI 2017-12-20 /pmc/articles/PMC6150000/ /pubmed/29261117 http://dx.doi.org/10.3390/molecules22122278 Text en © 2017 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Communication
Jian, Fangfang
Liu, E
Xu, Jiao
A Water Cluster Conduit in Crystal
title A Water Cluster Conduit in Crystal
title_full A Water Cluster Conduit in Crystal
title_fullStr A Water Cluster Conduit in Crystal
title_full_unstemmed A Water Cluster Conduit in Crystal
title_short A Water Cluster Conduit in Crystal
title_sort water cluster conduit in crystal
topic Communication
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6150000/
https://www.ncbi.nlm.nih.gov/pubmed/29261117
http://dx.doi.org/10.3390/molecules22122278
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AT xujiao waterclusterconduitincrystal

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