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Effect of Step Density and Orientation on the Apparent pH Dependence of Hydrogen and Hydroxide Adsorption on Stepped Platinum Surfaces
[Image: see text] The effect of the alkali-metal cation (Li(+), Na(+), K(+), and Cs(+)) on the non-Nernstian pH shift of the Pt(554) and Pt(533) step-associated voltammetric peak is elucidated over a wide pH window (1–13), through computation and experiment. In conjunction with our previously report...
Autores principales: | McCrum, Ian T., Chen, Xiaoting, Schwarz, Kathleen A., Janik, Michael J., Koper, Marc T. M. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical
Society
2018
|
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6150671/ https://www.ncbi.nlm.nih.gov/pubmed/30258524 http://dx.doi.org/10.1021/acs.jpcc.8b03660 |
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