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Study on the Fluorescent Activity of N(2)-Indolyl-1,2,3-triazole
A new type of blue emitter, N(2)-Indolyl-1,2,3-triazoles (NITs), with the λ(max) ranging from 420–480 nm and the Stokes shift from 89–143 nm, were synthesized through the coupling reaction of indoles with triazole derivatives. The influence of different substitution patterns on the optical propertie...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6151483/ https://www.ncbi.nlm.nih.gov/pubmed/28872608 http://dx.doi.org/10.3390/molecules22091380 |
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author | Zhang, You-Can Jin, Rui Li, Luo-Yuan Chen, Zili Fu, Li-Min |
author_facet | Zhang, You-Can Jin, Rui Li, Luo-Yuan Chen, Zili Fu, Li-Min |
author_sort | Zhang, You-Can |
collection | PubMed |
description | A new type of blue emitter, N(2)-Indolyl-1,2,3-triazoles (NITs), with the λ(max) ranging from 420–480 nm and the Stokes shift from 89–143 nm, were synthesized through the coupling reaction of indoles with triazole derivatives. The influence of different substitution patterns on the optical properties (efficiency, excitation, and emission wavelengths) of the NITs was investigated. In addition, one palladium complex were synthesized by using NITs as the ligands, which, however, exhibited no fluorescent activity, but did show the enhanced co-planarity. Lastly, two bio-active molecule derivatives were explored for the potential use of these novel dyes in related chemical and biological applications. |
format | Online Article Text |
id | pubmed-6151483 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2017 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-61514832018-11-13 Study on the Fluorescent Activity of N(2)-Indolyl-1,2,3-triazole Zhang, You-Can Jin, Rui Li, Luo-Yuan Chen, Zili Fu, Li-Min Molecules Communication A new type of blue emitter, N(2)-Indolyl-1,2,3-triazoles (NITs), with the λ(max) ranging from 420–480 nm and the Stokes shift from 89–143 nm, were synthesized through the coupling reaction of indoles with triazole derivatives. The influence of different substitution patterns on the optical properties (efficiency, excitation, and emission wavelengths) of the NITs was investigated. In addition, one palladium complex were synthesized by using NITs as the ligands, which, however, exhibited no fluorescent activity, but did show the enhanced co-planarity. Lastly, two bio-active molecule derivatives were explored for the potential use of these novel dyes in related chemical and biological applications. MDPI 2017-09-05 /pmc/articles/PMC6151483/ /pubmed/28872608 http://dx.doi.org/10.3390/molecules22091380 Text en © 2017 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Communication Zhang, You-Can Jin, Rui Li, Luo-Yuan Chen, Zili Fu, Li-Min Study on the Fluorescent Activity of N(2)-Indolyl-1,2,3-triazole |
title | Study on the Fluorescent Activity of N(2)-Indolyl-1,2,3-triazole |
title_full | Study on the Fluorescent Activity of N(2)-Indolyl-1,2,3-triazole |
title_fullStr | Study on the Fluorescent Activity of N(2)-Indolyl-1,2,3-triazole |
title_full_unstemmed | Study on the Fluorescent Activity of N(2)-Indolyl-1,2,3-triazole |
title_short | Study on the Fluorescent Activity of N(2)-Indolyl-1,2,3-triazole |
title_sort | study on the fluorescent activity of n(2)-indolyl-1,2,3-triazole |
topic | Communication |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6151483/ https://www.ncbi.nlm.nih.gov/pubmed/28872608 http://dx.doi.org/10.3390/molecules22091380 |
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