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Study on the Fluorescent Activity of N(2)-Indolyl-1,2,3-triazole

A new type of blue emitter, N(2)-Indolyl-1,2,3-triazoles (NITs), with the λ(max) ranging from 420–480 nm and the Stokes shift from 89–143 nm, were synthesized through the coupling reaction of indoles with triazole derivatives. The influence of different substitution patterns on the optical propertie...

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Detalles Bibliográficos
Autores principales: Zhang, You-Can, Jin, Rui, Li, Luo-Yuan, Chen, Zili, Fu, Li-Min
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6151483/
https://www.ncbi.nlm.nih.gov/pubmed/28872608
http://dx.doi.org/10.3390/molecules22091380
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author Zhang, You-Can
Jin, Rui
Li, Luo-Yuan
Chen, Zili
Fu, Li-Min
author_facet Zhang, You-Can
Jin, Rui
Li, Luo-Yuan
Chen, Zili
Fu, Li-Min
author_sort Zhang, You-Can
collection PubMed
description A new type of blue emitter, N(2)-Indolyl-1,2,3-triazoles (NITs), with the λ(max) ranging from 420–480 nm and the Stokes shift from 89–143 nm, were synthesized through the coupling reaction of indoles with triazole derivatives. The influence of different substitution patterns on the optical properties (efficiency, excitation, and emission wavelengths) of the NITs was investigated. In addition, one palladium complex were synthesized by using NITs as the ligands, which, however, exhibited no fluorescent activity, but did show the enhanced co-planarity. Lastly, two bio-active molecule derivatives were explored for the potential use of these novel dyes in related chemical and biological applications.
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spelling pubmed-61514832018-11-13 Study on the Fluorescent Activity of N(2)-Indolyl-1,2,3-triazole Zhang, You-Can Jin, Rui Li, Luo-Yuan Chen, Zili Fu, Li-Min Molecules Communication A new type of blue emitter, N(2)-Indolyl-1,2,3-triazoles (NITs), with the λ(max) ranging from 420–480 nm and the Stokes shift from 89–143 nm, were synthesized through the coupling reaction of indoles with triazole derivatives. The influence of different substitution patterns on the optical properties (efficiency, excitation, and emission wavelengths) of the NITs was investigated. In addition, one palladium complex were synthesized by using NITs as the ligands, which, however, exhibited no fluorescent activity, but did show the enhanced co-planarity. Lastly, two bio-active molecule derivatives were explored for the potential use of these novel dyes in related chemical and biological applications. MDPI 2017-09-05 /pmc/articles/PMC6151483/ /pubmed/28872608 http://dx.doi.org/10.3390/molecules22091380 Text en © 2017 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Communication
Zhang, You-Can
Jin, Rui
Li, Luo-Yuan
Chen, Zili
Fu, Li-Min
Study on the Fluorescent Activity of N(2)-Indolyl-1,2,3-triazole
title Study on the Fluorescent Activity of N(2)-Indolyl-1,2,3-triazole
title_full Study on the Fluorescent Activity of N(2)-Indolyl-1,2,3-triazole
title_fullStr Study on the Fluorescent Activity of N(2)-Indolyl-1,2,3-triazole
title_full_unstemmed Study on the Fluorescent Activity of N(2)-Indolyl-1,2,3-triazole
title_short Study on the Fluorescent Activity of N(2)-Indolyl-1,2,3-triazole
title_sort study on the fluorescent activity of n(2)-indolyl-1,2,3-triazole
topic Communication
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6151483/
https://www.ncbi.nlm.nih.gov/pubmed/28872608
http://dx.doi.org/10.3390/molecules22091380
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