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Dichlorotrifluoromethoxyacetic Acid: Preparation and Reactivity †
We describe the first gram scale preparation of the reagent dichlorotrifluoromethoxyacetic acid. This stable compound is obtained in five steps starting from the cheap diethylene glycol. The reactivity of the sodium salt of this fluorinated acid was also tested and allowed the preparation of new ami...
| Autores principales: | , , , , , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
MDPI
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6152670/ https://www.ncbi.nlm.nih.gov/pubmed/28598373 http://dx.doi.org/10.3390/molecules22060966 |
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| author | Zriba, Riadh Desmarchelier, Alaric Cadoret, Frédéric Bouvet, Sébastien Barthelemy, Anne-Laure Pégot, Bruce Diter, Patrick Dagousset, Guillaume Blazejewski, Jean-Claude Anselmi, Elsa Yagupolskii, Yurii Magnier, Emmanuel |
| author_facet | Zriba, Riadh Desmarchelier, Alaric Cadoret, Frédéric Bouvet, Sébastien Barthelemy, Anne-Laure Pégot, Bruce Diter, Patrick Dagousset, Guillaume Blazejewski, Jean-Claude Anselmi, Elsa Yagupolskii, Yurii Magnier, Emmanuel |
| author_sort | Zriba, Riadh |
| collection | PubMed |
| description | We describe the first gram scale preparation of the reagent dichlorotrifluoromethoxyacetic acid. This stable compound is obtained in five steps starting from the cheap diethylene glycol. The reactivity of the sodium salt of this fluorinated acid was also tested and allowed the preparation of new amides. |
| format | Online Article Text |
| id | pubmed-6152670 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2017 |
| publisher | MDPI |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-61526702018-11-13 Dichlorotrifluoromethoxyacetic Acid: Preparation and Reactivity † Zriba, Riadh Desmarchelier, Alaric Cadoret, Frédéric Bouvet, Sébastien Barthelemy, Anne-Laure Pégot, Bruce Diter, Patrick Dagousset, Guillaume Blazejewski, Jean-Claude Anselmi, Elsa Yagupolskii, Yurii Magnier, Emmanuel Molecules Article We describe the first gram scale preparation of the reagent dichlorotrifluoromethoxyacetic acid. This stable compound is obtained in five steps starting from the cheap diethylene glycol. The reactivity of the sodium salt of this fluorinated acid was also tested and allowed the preparation of new amides. MDPI 2017-06-09 /pmc/articles/PMC6152670/ /pubmed/28598373 http://dx.doi.org/10.3390/molecules22060966 Text en © 2017 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). |
| spellingShingle | Article Zriba, Riadh Desmarchelier, Alaric Cadoret, Frédéric Bouvet, Sébastien Barthelemy, Anne-Laure Pégot, Bruce Diter, Patrick Dagousset, Guillaume Blazejewski, Jean-Claude Anselmi, Elsa Yagupolskii, Yurii Magnier, Emmanuel Dichlorotrifluoromethoxyacetic Acid: Preparation and Reactivity † |
| title | Dichlorotrifluoromethoxyacetic Acid: Preparation and Reactivity † |
| title_full | Dichlorotrifluoromethoxyacetic Acid: Preparation and Reactivity † |
| title_fullStr | Dichlorotrifluoromethoxyacetic Acid: Preparation and Reactivity † |
| title_full_unstemmed | Dichlorotrifluoromethoxyacetic Acid: Preparation and Reactivity † |
| title_short | Dichlorotrifluoromethoxyacetic Acid: Preparation and Reactivity † |
| title_sort | dichlorotrifluoromethoxyacetic acid: preparation and reactivity † |
| topic | Article |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6152670/ https://www.ncbi.nlm.nih.gov/pubmed/28598373 http://dx.doi.org/10.3390/molecules22060966 |
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