Atom Efficient Preparation of Zinc Selenates for the Synthesis of Selenol Esters under “On Water” Conditions

We describe here an atom efficient procedure to prepare selenol esters in good to excellent yields by reacting [(PhSe)(2)Zn] or [(PhSe)(2)Zn]TMEDA with acyl chlorides under “on water” conditions. The method is applicable to a series of aromatic and aliphatic acyl chlorides and tolerates the presence...

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Detalles Bibliográficos
Autores principales: Sancineto, Luca, Pinto Vargas, Jaqueline, Monti, Bonifacio, Arca, Massimiliano, Lippolis, Vito, Perin, Gelson, Lenardao, Eder Joao, Santi, Claudio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2017
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6152685/
https://www.ncbi.nlm.nih.gov/pubmed/28594361
http://dx.doi.org/10.3390/molecules22060953
Descripción
Sumario:We describe here an atom efficient procedure to prepare selenol esters in good to excellent yields by reacting [(PhSe)(2)Zn] or [(PhSe)(2)Zn]TMEDA with acyl chlorides under “on water” conditions. The method is applicable to a series of aromatic and aliphatic acyl chlorides and tolerates the presence of other functionalities in the starting material.

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