Atom Efficient Preparation of Zinc Selenates for the Synthesis of Selenol Esters under “On Water” Conditions

We describe here an atom efficient procedure to prepare selenol esters in good to excellent yields by reacting [(PhSe)(2)Zn] or [(PhSe)(2)Zn]TMEDA with acyl chlorides under “on water” conditions. The method is applicable to a series of aromatic and aliphatic acyl chlorides and tolerates the presence...

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Autores principales: Sancineto, Luca, Pinto Vargas, Jaqueline, Monti, Bonifacio, Arca, Massimiliano, Lippolis, Vito, Perin, Gelson, Lenardao, Eder Joao, Santi, Claudio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2017
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6152685/
https://www.ncbi.nlm.nih.gov/pubmed/28594361
http://dx.doi.org/10.3390/molecules22060953
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author Sancineto, Luca
Pinto Vargas, Jaqueline
Monti, Bonifacio
Arca, Massimiliano
Lippolis, Vito
Perin, Gelson
Lenardao, Eder Joao
Santi, Claudio
author_facet Sancineto, Luca
Pinto Vargas, Jaqueline
Monti, Bonifacio
Arca, Massimiliano
Lippolis, Vito
Perin, Gelson
Lenardao, Eder Joao
Santi, Claudio
author_sort Sancineto, Luca
collection PubMed
description We describe here an atom efficient procedure to prepare selenol esters in good to excellent yields by reacting [(PhSe)(2)Zn] or [(PhSe)(2)Zn]TMEDA with acyl chlorides under “on water” conditions. The method is applicable to a series of aromatic and aliphatic acyl chlorides and tolerates the presence of other functionalities in the starting material.
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spelling pubmed-61526852018-11-13 Atom Efficient Preparation of Zinc Selenates for the Synthesis of Selenol Esters under “On Water” Conditions Sancineto, Luca Pinto Vargas, Jaqueline Monti, Bonifacio Arca, Massimiliano Lippolis, Vito Perin, Gelson Lenardao, Eder Joao Santi, Claudio Molecules Article We describe here an atom efficient procedure to prepare selenol esters in good to excellent yields by reacting [(PhSe)(2)Zn] or [(PhSe)(2)Zn]TMEDA with acyl chlorides under “on water” conditions. The method is applicable to a series of aromatic and aliphatic acyl chlorides and tolerates the presence of other functionalities in the starting material. MDPI 2017-06-08 /pmc/articles/PMC6152685/ /pubmed/28594361 http://dx.doi.org/10.3390/molecules22060953 Text en © 2017 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Sancineto, Luca
Pinto Vargas, Jaqueline
Monti, Bonifacio
Arca, Massimiliano
Lippolis, Vito
Perin, Gelson
Lenardao, Eder Joao
Santi, Claudio
Atom Efficient Preparation of Zinc Selenates for the Synthesis of Selenol Esters under “On Water” Conditions
title Atom Efficient Preparation of Zinc Selenates for the Synthesis of Selenol Esters under “On Water” Conditions
title_full Atom Efficient Preparation of Zinc Selenates for the Synthesis of Selenol Esters under “On Water” Conditions
title_fullStr Atom Efficient Preparation of Zinc Selenates for the Synthesis of Selenol Esters under “On Water” Conditions
title_full_unstemmed Atom Efficient Preparation of Zinc Selenates for the Synthesis of Selenol Esters under “On Water” Conditions
title_short Atom Efficient Preparation of Zinc Selenates for the Synthesis of Selenol Esters under “On Water” Conditions
title_sort atom efficient preparation of zinc selenates for the synthesis of selenol esters under “on water” conditions
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6152685/
https://www.ncbi.nlm.nih.gov/pubmed/28594361
http://dx.doi.org/10.3390/molecules22060953
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