Photoreactions of Endohedral Metallofullerene with Siliranes: Electronic Properties of Carbosilylated Lu(3)N@I(h)-C(80) †

Photochemical carbosilylation of Lu(3)N@I(h)-C(80) was performed using siliranes (silacyclopropanes) to afford the corresponding [5,6]- and [6,6]-adducts. Electrochemical studies indicated that the redox potentials of the carbosilylated derivatives were shifted cathodically in comparison with those...

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Detalles Bibliográficos
Autores principales: Kako, Masahiro, Minami, Kazuya, Kuroiwa, Taiki, Fukazawa, Shinpei, Arikawa, Yuki, Yamada, Michio, Maeda, Yutaka, Li, Qiao-Zhi, Nagase, Shigeru, Akasaka, Takeshi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2017
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6154294/
https://www.ncbi.nlm.nih.gov/pubmed/28531116
http://dx.doi.org/10.3390/molecules22050850
Descripción
Sumario:Photochemical carbosilylation of Lu(3)N@I(h)-C(80) was performed using siliranes (silacyclopropanes) to afford the corresponding [5,6]- and [6,6]-adducts. Electrochemical studies indicated that the redox potentials of the carbosilylated derivatives were shifted cathodically in comparison with those of the [5,6]-pyrrolidino adducts. The electronic effect of the silirane addends on Lu(3)N@I(h)-C(80) was verified on the basis of density functional theory calculations.

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