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Photoreactions of Endohedral Metallofullerene with Siliranes: Electronic Properties of Carbosilylated Lu(3)N@I(h)-C(80) †
Photochemical carbosilylation of Lu(3)N@I(h)-C(80) was performed using siliranes (silacyclopropanes) to afford the corresponding [5,6]- and [6,6]-adducts. Electrochemical studies indicated that the redox potentials of the carbosilylated derivatives were shifted cathodically in comparison with those...
| Autores principales: | , , , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
MDPI
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6154294/ https://www.ncbi.nlm.nih.gov/pubmed/28531116 http://dx.doi.org/10.3390/molecules22050850 |
| _version_ | 1783357667169796096 |
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| author | Kako, Masahiro Minami, Kazuya Kuroiwa, Taiki Fukazawa, Shinpei Arikawa, Yuki Yamada, Michio Maeda, Yutaka Li, Qiao-Zhi Nagase, Shigeru Akasaka, Takeshi |
| author_facet | Kako, Masahiro Minami, Kazuya Kuroiwa, Taiki Fukazawa, Shinpei Arikawa, Yuki Yamada, Michio Maeda, Yutaka Li, Qiao-Zhi Nagase, Shigeru Akasaka, Takeshi |
| author_sort | Kako, Masahiro |
| collection | PubMed |
| description | Photochemical carbosilylation of Lu(3)N@I(h)-C(80) was performed using siliranes (silacyclopropanes) to afford the corresponding [5,6]- and [6,6]-adducts. Electrochemical studies indicated that the redox potentials of the carbosilylated derivatives were shifted cathodically in comparison with those of the [5,6]-pyrrolidino adducts. The electronic effect of the silirane addends on Lu(3)N@I(h)-C(80) was verified on the basis of density functional theory calculations. |
| format | Online Article Text |
| id | pubmed-6154294 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2017 |
| publisher | MDPI |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-61542942018-11-13 Photoreactions of Endohedral Metallofullerene with Siliranes: Electronic Properties of Carbosilylated Lu(3)N@I(h)-C(80) † Kako, Masahiro Minami, Kazuya Kuroiwa, Taiki Fukazawa, Shinpei Arikawa, Yuki Yamada, Michio Maeda, Yutaka Li, Qiao-Zhi Nagase, Shigeru Akasaka, Takeshi Molecules Article Photochemical carbosilylation of Lu(3)N@I(h)-C(80) was performed using siliranes (silacyclopropanes) to afford the corresponding [5,6]- and [6,6]-adducts. Electrochemical studies indicated that the redox potentials of the carbosilylated derivatives were shifted cathodically in comparison with those of the [5,6]-pyrrolidino adducts. The electronic effect of the silirane addends on Lu(3)N@I(h)-C(80) was verified on the basis of density functional theory calculations. MDPI 2017-05-20 /pmc/articles/PMC6154294/ /pubmed/28531116 http://dx.doi.org/10.3390/molecules22050850 Text en © 2017 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). |
| spellingShingle | Article Kako, Masahiro Minami, Kazuya Kuroiwa, Taiki Fukazawa, Shinpei Arikawa, Yuki Yamada, Michio Maeda, Yutaka Li, Qiao-Zhi Nagase, Shigeru Akasaka, Takeshi Photoreactions of Endohedral Metallofullerene with Siliranes: Electronic Properties of Carbosilylated Lu(3)N@I(h)-C(80) † |
| title | Photoreactions of Endohedral Metallofullerene with Siliranes: Electronic Properties of Carbosilylated Lu(3)N@I(h)-C(80)
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| title_full | Photoreactions of Endohedral Metallofullerene with Siliranes: Electronic Properties of Carbosilylated Lu(3)N@I(h)-C(80)
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| title_fullStr | Photoreactions of Endohedral Metallofullerene with Siliranes: Electronic Properties of Carbosilylated Lu(3)N@I(h)-C(80)
† |
| title_full_unstemmed | Photoreactions of Endohedral Metallofullerene with Siliranes: Electronic Properties of Carbosilylated Lu(3)N@I(h)-C(80)
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| title_short | Photoreactions of Endohedral Metallofullerene with Siliranes: Electronic Properties of Carbosilylated Lu(3)N@I(h)-C(80)
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| title_sort | photoreactions of endohedral metallofullerene with siliranes: electronic properties of carbosilylated lu(3)n@i(h)-c(80)
† |
| topic | Article |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6154294/ https://www.ncbi.nlm.nih.gov/pubmed/28531116 http://dx.doi.org/10.3390/molecules22050850 |
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