Electrophilic Selenium Catalysis with Electrophilic N-F Reagents as the Oxidants

A suitable oxidative system is crucial to electrophilic selenium catalysis (ESC). This short review offers the overview of recent development in ESC with electrophilic N-F reagents as the oxidants. Several highly selective transformations of alkenes such as allylic or vinylic imidation, pyridination...

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Detalles Bibliográficos
Autores principales: Guo, Ruizhi, Liao, Lihao, Zhao, Xiaodan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2017
Materias:
Review
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6154571/
https://www.ncbi.nlm.nih.gov/pubmed/28534837
http://dx.doi.org/10.3390/molecules22050835
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author Guo, Ruizhi
Liao, Lihao
Zhao, Xiaodan
author_facet Guo, Ruizhi
Liao, Lihao
Zhao, Xiaodan
author_sort Guo, Ruizhi
collection PubMed
description A suitable oxidative system is crucial to electrophilic selenium catalysis (ESC). This short review offers the overview of recent development in ESC with electrophilic N-F reagents as the oxidants. Several highly selective transformations of alkenes such as allylic or vinylic imidation, pyridination, syn-dichlorination, oxidative cyclization and asymmetric cyclization have been described.
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spelling pubmed-61545712018-11-13 Electrophilic Selenium Catalysis with Electrophilic N-F Reagents as the Oxidants Guo, Ruizhi Liao, Lihao Zhao, Xiaodan Molecules Review A suitable oxidative system is crucial to electrophilic selenium catalysis (ESC). This short review offers the overview of recent development in ESC with electrophilic N-F reagents as the oxidants. Several highly selective transformations of alkenes such as allylic or vinylic imidation, pyridination, syn-dichlorination, oxidative cyclization and asymmetric cyclization have been described. MDPI 2017-05-19 /pmc/articles/PMC6154571/ /pubmed/28534837 http://dx.doi.org/10.3390/molecules22050835 Text en © 2017 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Review
Guo, Ruizhi
Liao, Lihao
Zhao, Xiaodan
Electrophilic Selenium Catalysis with Electrophilic N-F Reagents as the Oxidants
title Electrophilic Selenium Catalysis with Electrophilic N-F Reagents as the Oxidants
title_full Electrophilic Selenium Catalysis with Electrophilic N-F Reagents as the Oxidants
title_fullStr Electrophilic Selenium Catalysis with Electrophilic N-F Reagents as the Oxidants
title_full_unstemmed Electrophilic Selenium Catalysis with Electrophilic N-F Reagents as the Oxidants
title_short Electrophilic Selenium Catalysis with Electrophilic N-F Reagents as the Oxidants
title_sort electrophilic selenium catalysis with electrophilic n-f reagents as the oxidants
topic Review
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6154571/
https://www.ncbi.nlm.nih.gov/pubmed/28534837
http://dx.doi.org/10.3390/molecules22050835
work_keys_str_mv AT guoruizhi electrophilicseleniumcatalysiswithelectrophilicnfreagentsastheoxidants
AT liaolihao electrophilicseleniumcatalysiswithelectrophilicnfreagentsastheoxidants
AT zhaoxiaodan electrophilicseleniumcatalysiswithelectrophilicnfreagentsastheoxidants

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