Expeditious Synthesis of Dianionic-Headed 4-Sulfoalkanoic Acid Surfactants

4-Sulfoalkanoic acids are a class of important dianionic-headed surfactants. Various 4-sulfoalkanoic acids with straight C8, C10, C12, C14, C16, and C18 chains were synthesized expeditiously through the radical addition of methyl 2-((ethoxycarbonothioyl)thio)acetate to linear terminal olefins and su...

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Autores principales: Jiang, Jianhui, Xu, Jiaxi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2017
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6154584/
https://www.ncbi.nlm.nih.gov/pubmed/28420159
http://dx.doi.org/10.3390/molecules22040640
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author Jiang, Jianhui
Xu, Jiaxi
author_facet Jiang, Jianhui
Xu, Jiaxi
author_sort Jiang, Jianhui
collection PubMed
description 4-Sulfoalkanoic acids are a class of important dianionic-headed surfactants. Various 4-sulfoalkanoic acids with straight C8, C10, C12, C14, C16, and C18 chains were synthesized expeditiously through the radical addition of methyl 2-((ethoxycarbonothioyl)thio)acetate to linear terminal olefins and subsequent oxidation with peroxyformic acid. This is a useful and convenient strategy for the synthesis of dianionic-headed surfactants with a carboxylic acid and sulfonic acid functionalities in the head group region.
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spelling pubmed-61545842018-11-13 Expeditious Synthesis of Dianionic-Headed 4-Sulfoalkanoic Acid Surfactants Jiang, Jianhui Xu, Jiaxi Molecules Article 4-Sulfoalkanoic acids are a class of important dianionic-headed surfactants. Various 4-sulfoalkanoic acids with straight C8, C10, C12, C14, C16, and C18 chains were synthesized expeditiously through the radical addition of methyl 2-((ethoxycarbonothioyl)thio)acetate to linear terminal olefins and subsequent oxidation with peroxyformic acid. This is a useful and convenient strategy for the synthesis of dianionic-headed surfactants with a carboxylic acid and sulfonic acid functionalities in the head group region. MDPI 2017-04-16 /pmc/articles/PMC6154584/ /pubmed/28420159 http://dx.doi.org/10.3390/molecules22040640 Text en © 2017 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Jiang, Jianhui
Xu, Jiaxi
Expeditious Synthesis of Dianionic-Headed 4-Sulfoalkanoic Acid Surfactants
title Expeditious Synthesis of Dianionic-Headed 4-Sulfoalkanoic Acid Surfactants
title_full Expeditious Synthesis of Dianionic-Headed 4-Sulfoalkanoic Acid Surfactants
title_fullStr Expeditious Synthesis of Dianionic-Headed 4-Sulfoalkanoic Acid Surfactants
title_full_unstemmed Expeditious Synthesis of Dianionic-Headed 4-Sulfoalkanoic Acid Surfactants
title_short Expeditious Synthesis of Dianionic-Headed 4-Sulfoalkanoic Acid Surfactants
title_sort expeditious synthesis of dianionic-headed 4-sulfoalkanoic acid surfactants
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6154584/
https://www.ncbi.nlm.nih.gov/pubmed/28420159
http://dx.doi.org/10.3390/molecules22040640
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