Cargando…
Improved Synthesis of 1-O-Acyl-β-d-Glucopyranose Tetraacetates
An improved synthesis of 1-O-acyl glucosyl esters that avoids the use of expensive Ag reagents as well as the hydrolysis of unstable glucosyl bromides is reported. Notably, β-configuration products were obtained exclusively in good yields.
| Autores principales: | , , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
MDPI
2017
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6154585/ https://www.ncbi.nlm.nih.gov/pubmed/28430152 http://dx.doi.org/10.3390/molecules22040662 |
| _version_ | 1783357718202941440 |
|---|---|
| author | Chen, Yu Lu, Huan Chen, Yanyu Yu, Wansheng Dai, Hui Pan, Xianhua |
| author_facet | Chen, Yu Lu, Huan Chen, Yanyu Yu, Wansheng Dai, Hui Pan, Xianhua |
| author_sort | Chen, Yu |
| collection | PubMed |
| description | An improved synthesis of 1-O-acyl glucosyl esters that avoids the use of expensive Ag reagents as well as the hydrolysis of unstable glucosyl bromides is reported. Notably, β-configuration products were obtained exclusively in good yields. |
| format | Online Article Text |
| id | pubmed-6154585 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2017 |
| publisher | MDPI |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-61545852018-11-13 Improved Synthesis of 1-O-Acyl-β-d-Glucopyranose Tetraacetates Chen, Yu Lu, Huan Chen, Yanyu Yu, Wansheng Dai, Hui Pan, Xianhua Molecules Article An improved synthesis of 1-O-acyl glucosyl esters that avoids the use of expensive Ag reagents as well as the hydrolysis of unstable glucosyl bromides is reported. Notably, β-configuration products were obtained exclusively in good yields. MDPI 2017-04-21 /pmc/articles/PMC6154585/ /pubmed/28430152 http://dx.doi.org/10.3390/molecules22040662 Text en © 2017 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). |
| spellingShingle | Article Chen, Yu Lu, Huan Chen, Yanyu Yu, Wansheng Dai, Hui Pan, Xianhua Improved Synthesis of 1-O-Acyl-β-d-Glucopyranose Tetraacetates |
| title | Improved Synthesis of 1-O-Acyl-β-d-Glucopyranose Tetraacetates |
| title_full | Improved Synthesis of 1-O-Acyl-β-d-Glucopyranose Tetraacetates |
| title_fullStr | Improved Synthesis of 1-O-Acyl-β-d-Glucopyranose Tetraacetates |
| title_full_unstemmed | Improved Synthesis of 1-O-Acyl-β-d-Glucopyranose Tetraacetates |
| title_short | Improved Synthesis of 1-O-Acyl-β-d-Glucopyranose Tetraacetates |
| title_sort | improved synthesis of 1-o-acyl-β-d-glucopyranose tetraacetates |
| topic | Article |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6154585/ https://www.ncbi.nlm.nih.gov/pubmed/28430152 http://dx.doi.org/10.3390/molecules22040662 |
| work_keys_str_mv | AT chenyu improvedsynthesisof1oacylbdglucopyranosetetraacetates AT luhuan improvedsynthesisof1oacylbdglucopyranosetetraacetates AT chenyanyu improvedsynthesisof1oacylbdglucopyranosetetraacetates AT yuwansheng improvedsynthesisof1oacylbdglucopyranosetetraacetates AT daihui improvedsynthesisof1oacylbdglucopyranosetetraacetates AT panxianhua improvedsynthesisof1oacylbdglucopyranosetetraacetates |