Spirobifluorene Core-Based Novel Hole Transporting Materials for Red Phosphorescence OLEDs

Two new hole transporting materials, named HTM 1A and HTM 1B, were designed and synthesized in significant yields using the well-known Buchwald Hartwig and Suzuki cross- coupling reactions. Both materials showed higher decomposition temperatures (over 450 °C) at 5% weight reduction and HTM 1B exhibi...

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Detalles Bibliográficos
Autores principales: Braveenth, Ramanaskanda, Bae, Hyeong Woo, Nguyen, Quynh Pham Bao, Ko, Haye Min, Lee, Choong Hun, Kim, Hyeong Jun, Kwon, Jang Hyuk, Chai, Kyu Yun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2017
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6155350/
https://www.ncbi.nlm.nih.gov/pubmed/28335435
http://dx.doi.org/10.3390/molecules22030464
Descripción
Sumario:Two new hole transporting materials, named HTM 1A and HTM 1B, were designed and synthesized in significant yields using the well-known Buchwald Hartwig and Suzuki cross- coupling reactions. Both materials showed higher decomposition temperatures (over 450 °C) at 5% weight reduction and HTM 1B exhibited a higher glass transition temperature of 180 °C. Red phosphorescence-based OLED devices were fabricated to analyze the device performances compared to Spiro-NPB and NPB as reference hole transporting materials. Devices consist of hole transporting material as HTM 1B showed better maximum current and power efficiencies of 16.16 cd/A and 11.17 lm/W, at the same time it revealed an improved external quantum efficiency of 13.64%. This efficiency is considerably higher than that of Spiro-NPB and NPB-based reference devices.

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