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Advances in Solid-State Transformations of Coordination Bonds: From the Ball Mill to the Aging Chamber

Controlling the formation of coordination bonds is pivotal to the development of a plethora of functional metal-organic materials, ranging from coordination polymers, metal-organic frameworks (MOFs) to metallodrugs. The interest in and commercialization of such materials has created a need for more...

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Detalles Bibliográficos
Autores principales: Mottillo, Cristina, Friščić, Tomislav
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6155591/
https://www.ncbi.nlm.nih.gov/pubmed/28106754
http://dx.doi.org/10.3390/molecules22010144
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author Mottillo, Cristina
Friščić, Tomislav
author_facet Mottillo, Cristina
Friščić, Tomislav
author_sort Mottillo, Cristina
collection PubMed
description Controlling the formation of coordination bonds is pivotal to the development of a plethora of functional metal-organic materials, ranging from coordination polymers, metal-organic frameworks (MOFs) to metallodrugs. The interest in and commercialization of such materials has created a need for more efficient, environmentally-friendly routes for making coordination bonds. Solid-state coordination chemistry is a versatile greener alternative to conventional synthesis, offering quantitative yields, enhanced stoichiometric and topological selectivity, access to a wider range of precursors, as well as to molecules and materials not readily accessible in solution or solvothermally. With a focus on mechanochemical, thermochemical and “accelerated aging” approaches to coordination polymers, including pharmaceutically-relevant materials and microporous MOFs, this review highlights the recent advances in solid-state coordination chemistry and techniques for understanding the underlying reaction mechanisms.
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spelling pubmed-61555912018-11-13 Advances in Solid-State Transformations of Coordination Bonds: From the Ball Mill to the Aging Chamber Mottillo, Cristina Friščić, Tomislav Molecules Review Controlling the formation of coordination bonds is pivotal to the development of a plethora of functional metal-organic materials, ranging from coordination polymers, metal-organic frameworks (MOFs) to metallodrugs. The interest in and commercialization of such materials has created a need for more efficient, environmentally-friendly routes for making coordination bonds. Solid-state coordination chemistry is a versatile greener alternative to conventional synthesis, offering quantitative yields, enhanced stoichiometric and topological selectivity, access to a wider range of precursors, as well as to molecules and materials not readily accessible in solution or solvothermally. With a focus on mechanochemical, thermochemical and “accelerated aging” approaches to coordination polymers, including pharmaceutically-relevant materials and microporous MOFs, this review highlights the recent advances in solid-state coordination chemistry and techniques for understanding the underlying reaction mechanisms. MDPI 2017-01-17 /pmc/articles/PMC6155591/ /pubmed/28106754 http://dx.doi.org/10.3390/molecules22010144 Text en © 2017 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC-BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Review
Mottillo, Cristina
Friščić, Tomislav
Advances in Solid-State Transformations of Coordination Bonds: From the Ball Mill to the Aging Chamber
title Advances in Solid-State Transformations of Coordination Bonds: From the Ball Mill to the Aging Chamber
title_full Advances in Solid-State Transformations of Coordination Bonds: From the Ball Mill to the Aging Chamber
title_fullStr Advances in Solid-State Transformations of Coordination Bonds: From the Ball Mill to the Aging Chamber
title_full_unstemmed Advances in Solid-State Transformations of Coordination Bonds: From the Ball Mill to the Aging Chamber
title_short Advances in Solid-State Transformations of Coordination Bonds: From the Ball Mill to the Aging Chamber
title_sort advances in solid-state transformations of coordination bonds: from the ball mill to the aging chamber
topic Review
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6155591/
https://www.ncbi.nlm.nih.gov/pubmed/28106754
http://dx.doi.org/10.3390/molecules22010144
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