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Atom-Economic Synthesis of 4-Pyrones from Diynones and Water

Transition-metal-free synthesis of 4-pyrones via TfOH-promoted nucleophilic addition/cyclization of diynones and water has been developed. This transformation is simple, atom economical and environmentally benign, providing rapid and efficient access to substituted 4-pyrones.

Detalles Bibliográficos
Autores principales: Xu, Yan-Li, Teng, Qing-Hu, Tong, Wei, Wang, Heng-Shan, Pan, Ying-Ming, Ma, Xian-Li
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6155647/
https://www.ncbi.nlm.nih.gov/pubmed/28075414
http://dx.doi.org/10.3390/molecules22010109
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author Xu, Yan-Li
Teng, Qing-Hu
Tong, Wei
Wang, Heng-Shan
Pan, Ying-Ming
Ma, Xian-Li
author_facet Xu, Yan-Li
Teng, Qing-Hu
Tong, Wei
Wang, Heng-Shan
Pan, Ying-Ming
Ma, Xian-Li
author_sort Xu, Yan-Li
collection PubMed
description Transition-metal-free synthesis of 4-pyrones via TfOH-promoted nucleophilic addition/cyclization of diynones and water has been developed. This transformation is simple, atom economical and environmentally benign, providing rapid and efficient access to substituted 4-pyrones.
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spelling pubmed-61556472018-11-13 Atom-Economic Synthesis of 4-Pyrones from Diynones and Water Xu, Yan-Li Teng, Qing-Hu Tong, Wei Wang, Heng-Shan Pan, Ying-Ming Ma, Xian-Li Molecules Communication Transition-metal-free synthesis of 4-pyrones via TfOH-promoted nucleophilic addition/cyclization of diynones and water has been developed. This transformation is simple, atom economical and environmentally benign, providing rapid and efficient access to substituted 4-pyrones. MDPI 2017-01-10 /pmc/articles/PMC6155647/ /pubmed/28075414 http://dx.doi.org/10.3390/molecules22010109 Text en © 2017 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC-BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Communication
Xu, Yan-Li
Teng, Qing-Hu
Tong, Wei
Wang, Heng-Shan
Pan, Ying-Ming
Ma, Xian-Li
Atom-Economic Synthesis of 4-Pyrones from Diynones and Water
title Atom-Economic Synthesis of 4-Pyrones from Diynones and Water
title_full Atom-Economic Synthesis of 4-Pyrones from Diynones and Water
title_fullStr Atom-Economic Synthesis of 4-Pyrones from Diynones and Water
title_full_unstemmed Atom-Economic Synthesis of 4-Pyrones from Diynones and Water
title_short Atom-Economic Synthesis of 4-Pyrones from Diynones and Water
title_sort atom-economic synthesis of 4-pyrones from diynones and water
topic Communication
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6155647/
https://www.ncbi.nlm.nih.gov/pubmed/28075414
http://dx.doi.org/10.3390/molecules22010109
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AT wanghengshan atomeconomicsynthesisof4pyronesfromdiynonesandwater
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