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Atom-Economic Synthesis of 4-Pyrones from Diynones and Water
Transition-metal-free synthesis of 4-pyrones via TfOH-promoted nucleophilic addition/cyclization of diynones and water has been developed. This transformation is simple, atom economical and environmentally benign, providing rapid and efficient access to substituted 4-pyrones.
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6155647/ https://www.ncbi.nlm.nih.gov/pubmed/28075414 http://dx.doi.org/10.3390/molecules22010109 |
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author | Xu, Yan-Li Teng, Qing-Hu Tong, Wei Wang, Heng-Shan Pan, Ying-Ming Ma, Xian-Li |
author_facet | Xu, Yan-Li Teng, Qing-Hu Tong, Wei Wang, Heng-Shan Pan, Ying-Ming Ma, Xian-Li |
author_sort | Xu, Yan-Li |
collection | PubMed |
description | Transition-metal-free synthesis of 4-pyrones via TfOH-promoted nucleophilic addition/cyclization of diynones and water has been developed. This transformation is simple, atom economical and environmentally benign, providing rapid and efficient access to substituted 4-pyrones. |
format | Online Article Text |
id | pubmed-6155647 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2017 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-61556472018-11-13 Atom-Economic Synthesis of 4-Pyrones from Diynones and Water Xu, Yan-Li Teng, Qing-Hu Tong, Wei Wang, Heng-Shan Pan, Ying-Ming Ma, Xian-Li Molecules Communication Transition-metal-free synthesis of 4-pyrones via TfOH-promoted nucleophilic addition/cyclization of diynones and water has been developed. This transformation is simple, atom economical and environmentally benign, providing rapid and efficient access to substituted 4-pyrones. MDPI 2017-01-10 /pmc/articles/PMC6155647/ /pubmed/28075414 http://dx.doi.org/10.3390/molecules22010109 Text en © 2017 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC-BY) license (http://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Communication Xu, Yan-Li Teng, Qing-Hu Tong, Wei Wang, Heng-Shan Pan, Ying-Ming Ma, Xian-Li Atom-Economic Synthesis of 4-Pyrones from Diynones and Water |
title | Atom-Economic Synthesis of 4-Pyrones from Diynones and Water |
title_full | Atom-Economic Synthesis of 4-Pyrones from Diynones and Water |
title_fullStr | Atom-Economic Synthesis of 4-Pyrones from Diynones and Water |
title_full_unstemmed | Atom-Economic Synthesis of 4-Pyrones from Diynones and Water |
title_short | Atom-Economic Synthesis of 4-Pyrones from Diynones and Water |
title_sort | atom-economic synthesis of 4-pyrones from diynones and water |
topic | Communication |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6155647/ https://www.ncbi.nlm.nih.gov/pubmed/28075414 http://dx.doi.org/10.3390/molecules22010109 |
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