Preparation of “Constrained Geometry” Titanium Complexes of [1,2]Azasilinane Framework for Ethylene/1-Octene Copolymerization

The Me(2)Si-bridged ansa-Cp/amido half-metallocene, [Me(2)Si(η(5)-Me(4)C(5))(N(t)Bu)]TiCl(2), termed a “constrained-geometry catalyst (CGC)”, is a representative homogeneous Ziegler catalyst. CGC derivatives with the [1,2]azasilinane framework, in which the amide alkyl substituent is joined by the S...

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Detalles Bibliográficos
Autores principales: Lee, Seul, Park, Seung Soo, Kim, Jin Gu, Kim, Chung Sol, Lee, Bun Yeoul
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2017
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6155698/
https://www.ncbi.nlm.nih.gov/pubmed/28208780
http://dx.doi.org/10.3390/molecules22020258

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6155698/
https://www.ncbi.nlm.nih.gov/pubmed/28208780
http://dx.doi.org/10.3390/molecules22020258

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