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Preparation of “Constrained Geometry” Titanium Complexes of [1,2]Azasilinane Framework for Ethylene/1-Octene Copolymerization
The Me(2)Si-bridged ansa-Cp/amido half-metallocene, [Me(2)Si(η(5)-Me(4)C(5))(N(t)Bu)]TiCl(2), termed a “constrained-geometry catalyst (CGC)”, is a representative homogeneous Ziegler catalyst. CGC derivatives with the [1,2]azasilinane framework, in which the amide alkyl substituent is joined by the S...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
MDPI
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6155698/ https://www.ncbi.nlm.nih.gov/pubmed/28208780 http://dx.doi.org/10.3390/molecules22020258 |