Ultrasound-induced gelation of a giant macrocycle

A 68-membered macrocycle undergoes ultrasound-induced supramolecular gelation in acetonitrile. The sonogel shows a remarkable thermostability, indicating that self-assembly is mediated by exceptionally robust non-covalent interactions. Model compounds indicate that the macrocyclic topology is essent...

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Detalles Bibliográficos
Autores principales: Núñez-Villanueva, Diego, Jinks, Michael A., Gómez Magenti, Jorge, Hunter, Christopher A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6156880/
https://www.ncbi.nlm.nih.gov/pubmed/30204157
http://dx.doi.org/10.1039/c8cc04742a
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author Núñez-Villanueva, Diego
Jinks, Michael A.
Gómez Magenti, Jorge
Hunter, Christopher A.
author_facet Núñez-Villanueva, Diego
Jinks, Michael A.
Gómez Magenti, Jorge
Hunter, Christopher A.
author_sort Núñez-Villanueva, Diego
collection PubMed
description A 68-membered macrocycle undergoes ultrasound-induced supramolecular gelation in acetonitrile. The sonogel shows a remarkable thermostability, indicating that self-assembly is mediated by exceptionally robust non-covalent interactions. Model compounds indicate that the macrocyclic topology is essential for gelation to occur.
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spelling pubmed-61568802018-10-05 Ultrasound-induced gelation of a giant macrocycle Núñez-Villanueva, Diego Jinks, Michael A. Gómez Magenti, Jorge Hunter, Christopher A. Chem Commun (Camb) Chemistry A 68-membered macrocycle undergoes ultrasound-induced supramolecular gelation in acetonitrile. The sonogel shows a remarkable thermostability, indicating that self-assembly is mediated by exceptionally robust non-covalent interactions. Model compounds indicate that the macrocyclic topology is essential for gelation to occur. Royal Society of Chemistry 2018-10-04 2018-09-11 /pmc/articles/PMC6156880/ /pubmed/30204157 http://dx.doi.org/10.1039/c8cc04742a Text en This journal is © The Royal Society of Chemistry 2018 http://creativecommons.org/licenses/by/3.0/ This article is freely available. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence (CC BY 3.0)
spellingShingle Chemistry
Núñez-Villanueva, Diego
Jinks, Michael A.
Gómez Magenti, Jorge
Hunter, Christopher A.
Ultrasound-induced gelation of a giant macrocycle
title Ultrasound-induced gelation of a giant macrocycle
title_full Ultrasound-induced gelation of a giant macrocycle
title_fullStr Ultrasound-induced gelation of a giant macrocycle
title_full_unstemmed Ultrasound-induced gelation of a giant macrocycle
title_short Ultrasound-induced gelation of a giant macrocycle
title_sort ultrasound-induced gelation of a giant macrocycle
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6156880/
https://www.ncbi.nlm.nih.gov/pubmed/30204157
http://dx.doi.org/10.1039/c8cc04742a
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