Aqueous Phase Separation Behavior of Highly Syndiotactic, High Molecular Weight Polymers with Densely Packed Hydroxy-Containing Side Groups

[Image: see text] Herein we describe the Rh-catalyzed C1 polymerization of silyl-protected diazoacetates of the general formula HC(=N(2))C(=O)O(CH(2))(x)OSiR(3), where x = 2–5. After polymerization and subsequent desilylation, syndiotactic polymers bearing a hydroxy-containing side group on every ba...

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Detalles Bibliográficos
Autores principales: Tromp, Dorette S., Lankelma, Marianne, de Valk, Hannah, de Josselin de Jong, Emile, de Bruin, Bas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6158683/
https://www.ncbi.nlm.nih.gov/pubmed/30270941
http://dx.doi.org/10.1021/acs.macromol.8b01150

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