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Light-induced decarboxylation in a photo-responsive iron-containing complex based on polyoxometalate and oxalato ligands

A new photoresponsive molecular polyanion in which two Fe(iii) ions are simultaneously coordinated by two [A-α-PW(9)O(34)](9–) polyoxometalate units and two oxalato ligands has been obtained. When irradiated with UV light its potassium salt, 1, exhibits a remarkable photocoloration effect, attributa...

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Detalles Bibliográficos
Autores principales: Duan, Yan, Waerenborgh, João C., Clemente-Juan, Juan M., Giménez-Saiz, Carlos, Coronado, Eugenio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6166234/
https://www.ncbi.nlm.nih.gov/pubmed/30294411
http://dx.doi.org/10.1039/c6sc01919f