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Light-induced decarboxylation in a photo-responsive iron-containing complex based on polyoxometalate and oxalato ligands
A new photoresponsive molecular polyanion in which two Fe(iii) ions are simultaneously coordinated by two [A-α-PW(9)O(34)](9–) polyoxometalate units and two oxalato ligands has been obtained. When irradiated with UV light its potassium salt, 1, exhibits a remarkable photocoloration effect, attributa...
Autores principales: | Duan, Yan, Waerenborgh, João C., Clemente-Juan, Juan M., Giménez-Saiz, Carlos, Coronado, Eugenio |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6166234/ https://www.ncbi.nlm.nih.gov/pubmed/30294411 http://dx.doi.org/10.1039/c6sc01919f |
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