Cargando…
Direct Photochemical C–H Carboxylation of Aromatic Diamines with CO(2) under Electron-Donor- and Base-free Conditions
We report the photochemical carboxylation of o-phenylenedimamine in the absence of a base and an electron donor under an atmosphere of CO(2), which afforded 2,3-diaminobenzoic acid (DBA) in 28% synthetic yield and 0.22% quantum yield (Φ(%)). The synthetic yield of DBA in this reaction increased to 5...
| Autores principales: | , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Nature Publishing Group UK
2018
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6168591/ https://www.ncbi.nlm.nih.gov/pubmed/30279606 http://dx.doi.org/10.1038/s41598-018-33060-3 |