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Silver-Catalyzed Regio- and Stereoselective Formal Carbene Insertion into Unstrained C−C σ-Bonds of 1,3-Dicarbonyls

A regio- and stereoselective silver-catalyzed formal carbene insertion into 1,3-dicarbonyls has been developed, using N-nosylhydrazones as diazo surrogates. Two new C−C bonds are constructed at the carbenic carbon center through the selective cleavage of the C−C(=O) σ-bond of acyclic 1,3-dicarbonyls...

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Detalles Bibliográficos
Autores principales:	Liu, Zhaohong, Zhang, Xinyu, Virelli, Matteo, Zanoni, Giuseppe, Anderson, Edward A., Bi, Xihe
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Elsevier 2018
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6170519/ https://www.ncbi.nlm.nih.gov/pubmed/30278300 http://dx.doi.org/10.1016/j.isci.2018.09.006

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