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Colloids for Catalysts: A Concept for the Preparation of Superior Catalysts of Industrial Relevance
Compared to conventional preparation methods for supported heterogeneous catalysts, the use of colloidal nanoparticles (NPs) allows for a precise control over size, size distribution, and distribution/location of the NPs on the support. However, common colloidal syntheses have restrictions that limi...
Autores principales: | , , , , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6175418/ https://www.ncbi.nlm.nih.gov/pubmed/30051948 http://dx.doi.org/10.1002/anie.201807450 |
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author | Quinson, Jonathan Neumann, Sara Wannmacher, Tanja Kacenauskaite, Laura Inaba, Masanori Bucher, Jan Bizzotto, Francesco Simonsen, Søren B. Theil Kuhn, Luise Bujak, Dajana Zana, Alessandro Arenz, Matthias Kunz, Sebastian |
author_facet | Quinson, Jonathan Neumann, Sara Wannmacher, Tanja Kacenauskaite, Laura Inaba, Masanori Bucher, Jan Bizzotto, Francesco Simonsen, Søren B. Theil Kuhn, Luise Bujak, Dajana Zana, Alessandro Arenz, Matthias Kunz, Sebastian |
author_sort | Quinson, Jonathan |
collection | PubMed |
description | Compared to conventional preparation methods for supported heterogeneous catalysts, the use of colloidal nanoparticles (NPs) allows for a precise control over size, size distribution, and distribution/location of the NPs on the support. However, common colloidal syntheses have restrictions that limit their applicability for industrial catalyst preparation. We present a simple, surfactant‐free, and scalable preparation method for colloidal NPs to overcome these restrictions. We demonstrate how precious‐metal NPs are prepared in alkaline methanol, how the particle size can be tuned, and how supported catalysts are obtained. The potential of these colloids in the preparation of improved catalysts is demonstrated by two examples from heterogeneous catalysis and electrocatalysis. |
format | Online Article Text |
id | pubmed-6175418 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2018 |
publisher | John Wiley and Sons Inc. |
record_format | MEDLINE/PubMed |
spelling | pubmed-61754182018-10-19 Colloids for Catalysts: A Concept for the Preparation of Superior Catalysts of Industrial Relevance Quinson, Jonathan Neumann, Sara Wannmacher, Tanja Kacenauskaite, Laura Inaba, Masanori Bucher, Jan Bizzotto, Francesco Simonsen, Søren B. Theil Kuhn, Luise Bujak, Dajana Zana, Alessandro Arenz, Matthias Kunz, Sebastian Angew Chem Int Ed Engl Communications Compared to conventional preparation methods for supported heterogeneous catalysts, the use of colloidal nanoparticles (NPs) allows for a precise control over size, size distribution, and distribution/location of the NPs on the support. However, common colloidal syntheses have restrictions that limit their applicability for industrial catalyst preparation. We present a simple, surfactant‐free, and scalable preparation method for colloidal NPs to overcome these restrictions. We demonstrate how precious‐metal NPs are prepared in alkaline methanol, how the particle size can be tuned, and how supported catalysts are obtained. The potential of these colloids in the preparation of improved catalysts is demonstrated by two examples from heterogeneous catalysis and electrocatalysis. John Wiley and Sons Inc. 2018-08-23 2018-09-17 /pmc/articles/PMC6175418/ /pubmed/30051948 http://dx.doi.org/10.1002/anie.201807450 Text en © 2018 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc-nd/4.0/ License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non‐commercial and no modifications or adaptations are made. |
spellingShingle | Communications Quinson, Jonathan Neumann, Sara Wannmacher, Tanja Kacenauskaite, Laura Inaba, Masanori Bucher, Jan Bizzotto, Francesco Simonsen, Søren B. Theil Kuhn, Luise Bujak, Dajana Zana, Alessandro Arenz, Matthias Kunz, Sebastian Colloids for Catalysts: A Concept for the Preparation of Superior Catalysts of Industrial Relevance |
title | Colloids for Catalysts: A Concept for the Preparation of Superior Catalysts of Industrial Relevance |
title_full | Colloids for Catalysts: A Concept for the Preparation of Superior Catalysts of Industrial Relevance |
title_fullStr | Colloids for Catalysts: A Concept for the Preparation of Superior Catalysts of Industrial Relevance |
title_full_unstemmed | Colloids for Catalysts: A Concept for the Preparation of Superior Catalysts of Industrial Relevance |
title_short | Colloids for Catalysts: A Concept for the Preparation of Superior Catalysts of Industrial Relevance |
title_sort | colloids for catalysts: a concept for the preparation of superior catalysts of industrial relevance |
topic | Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6175418/ https://www.ncbi.nlm.nih.gov/pubmed/30051948 http://dx.doi.org/10.1002/anie.201807450 |
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