(NH(4))Ga(HAsO(4))(2) and TlAl(HAsO(4))(2) - two new RbFe(HPO(4))(2)-type M (+) M (3+) arsenates

The crystal structures of hydro­thermally synthesized (T = 493 K, 7–9 d) ammonium gallium bis­[hydrogen arsenate(V)], (NH(4))Ga(HAsO(4))(2), and thallium aluminium bis­[hydrogen arsenate(V)], TlAl(HAsO(4))(2), were solved by single-crystal X-ray diffraction. Both compounds crystallize in the common...

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Detalles Bibliográficos
Autores principales: Schwendtner, Karolina, Kolitsch, Uwe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2018
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6176428/
https://www.ncbi.nlm.nih.gov/pubmed/30319811
http://dx.doi.org/10.1107/S2056989018013567
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author Schwendtner, Karolina
Kolitsch, Uwe
author_facet Schwendtner, Karolina
Kolitsch, Uwe
author_sort Schwendtner, Karolina
collection PubMed
description The crystal structures of hydro­thermally synthesized (T = 493 K, 7–9 d) ammonium gallium bis­[hydrogen arsenate(V)], (NH(4))Ga(HAsO(4))(2), and thallium aluminium bis­[hydrogen arsenate(V)], TlAl(HAsO(4))(2), were solved by single-crystal X-ray diffraction. Both compounds crystallize in the common RbFe(HPO(4))(2) structure type (R [Image: see text] c) and share the same tetra­hedral–octa­hedral framework topology that houses the M (+) cations in its channels. One of the two Tl sites is slightly offset from its ideal position. Strong O—H⋯O hydrogen bonds strengthen the network.
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spelling pubmed-61764282018-10-12 (NH(4))Ga(HAsO(4))(2) and TlAl(HAsO(4))(2) - two new RbFe(HPO(4))(2)-type M (+) M (3+) arsenates Schwendtner, Karolina Kolitsch, Uwe Acta Crystallogr E Crystallogr Commun Research Communications The crystal structures of hydro­thermally synthesized (T = 493 K, 7–9 d) ammonium gallium bis­[hydrogen arsenate(V)], (NH(4))Ga(HAsO(4))(2), and thallium aluminium bis­[hydrogen arsenate(V)], TlAl(HAsO(4))(2), were solved by single-crystal X-ray diffraction. Both compounds crystallize in the common RbFe(HPO(4))(2) structure type (R [Image: see text] c) and share the same tetra­hedral–octa­hedral framework topology that houses the M (+) cations in its channels. One of the two Tl sites is slightly offset from its ideal position. Strong O—H⋯O hydrogen bonds strengthen the network. International Union of Crystallography 2018-09-28 /pmc/articles/PMC6176428/ /pubmed/30319811 http://dx.doi.org/10.1107/S2056989018013567 Text en © Schwendtner and Kolitsch 2018 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Schwendtner, Karolina
Kolitsch, Uwe
(NH(4))Ga(HAsO(4))(2) and TlAl(HAsO(4))(2) - two new RbFe(HPO(4))(2)-type M (+) M (3+) arsenates
title (NH(4))Ga(HAsO(4))(2) and TlAl(HAsO(4))(2) - two new RbFe(HPO(4))(2)-type M (+) M (3+) arsenates
title_full (NH(4))Ga(HAsO(4))(2) and TlAl(HAsO(4))(2) - two new RbFe(HPO(4))(2)-type M (+) M (3+) arsenates
title_fullStr (NH(4))Ga(HAsO(4))(2) and TlAl(HAsO(4))(2) - two new RbFe(HPO(4))(2)-type M (+) M (3+) arsenates
title_full_unstemmed (NH(4))Ga(HAsO(4))(2) and TlAl(HAsO(4))(2) - two new RbFe(HPO(4))(2)-type M (+) M (3+) arsenates
title_short (NH(4))Ga(HAsO(4))(2) and TlAl(HAsO(4))(2) - two new RbFe(HPO(4))(2)-type M (+) M (3+) arsenates
title_sort (nh(4))ga(haso(4))(2) and tlal(haso(4))(2) - two new rbfe(hpo(4))(2)-type m (+) m (3+) arsenates
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6176428/
https://www.ncbi.nlm.nih.gov/pubmed/30319811
http://dx.doi.org/10.1107/S2056989018013567
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