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Crystal structure of ethyl 4-[4-(di­methyl­amino)­phen­yl]-2,7,7-trimethyl-5-oxo-1,4,5,6,7,8-hexa­hydro­quinoline-3-carboxyl­ate

In the title racemic compound, ethyl 4-(4-di­methyl­amino­phen­yl)-2,7,7-trimethyl-5-oxo-1,4,5,6,7,8-hexa­hydro­quinoline-3-carboxyl­ate, the common structural features in this type of compound, such as the flat-boat conformation of the 1,4-di­hydro­pyridine (1,4-DHP) ring, the envelope conformation...

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Detalles Bibliográficos
Autores principales: Steiger, Scott A., Li, Chun, Natale, Nicholas R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6176430/
https://www.ncbi.nlm.nih.gov/pubmed/30319791
http://dx.doi.org/10.1107/S2056989018011982
Descripción
Sumario:In the title racemic compound, ethyl 4-(4-di­methyl­amino­phen­yl)-2,7,7-trimethyl-5-oxo-1,4,5,6,7,8-hexa­hydro­quinoline-3-carboxyl­ate, the common structural features in this type of compound, such as the flat-boat conformation of the 1,4-di­hydro­pyridine (1,4-DHP) ring, the envelope conformation of the fused cyclo­hexa­none, and the substituted phenyl ring at the pseudo-axial position and orthogonal to the 1,4-DHP ring, are present. In the crystal, mol­ecules are linked via N—H⋯O and C—H⋯O hydrogen bonds, forming layers parallel to the (10[Image: see text]) plane.