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Crystal structure of ethyl 4-[4-(di­methyl­amino)­phen­yl]-2,7,7-trimethyl-5-oxo-1,4,5,6,7,8-hexa­hydro­quinoline-3-carboxyl­ate

In the title racemic compound, ethyl 4-(4-di­methyl­amino­phen­yl)-2,7,7-trimethyl-5-oxo-1,4,5,6,7,8-hexa­hydro­quinoline-3-carboxyl­ate, the common structural features in this type of compound, such as the flat-boat conformation of the 1,4-di­hydro­pyridine (1,4-DHP) ring, the envelope conformation...

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Detalles Bibliográficos
Autores principales: Steiger, Scott A., Li, Chun, Natale, Nicholas R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6176430/
https://www.ncbi.nlm.nih.gov/pubmed/30319791
http://dx.doi.org/10.1107/S2056989018011982
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author Steiger, Scott A.
Li, Chun
Natale, Nicholas R.
author_facet Steiger, Scott A.
Li, Chun
Natale, Nicholas R.
author_sort Steiger, Scott A.
collection PubMed
description In the title racemic compound, ethyl 4-(4-di­methyl­amino­phen­yl)-2,7,7-trimethyl-5-oxo-1,4,5,6,7,8-hexa­hydro­quinoline-3-carboxyl­ate, the common structural features in this type of compound, such as the flat-boat conformation of the 1,4-di­hydro­pyridine (1,4-DHP) ring, the envelope conformation of the fused cyclo­hexa­none, and the substituted phenyl ring at the pseudo-axial position and orthogonal to the 1,4-DHP ring, are present. In the crystal, mol­ecules are linked via N—H⋯O and C—H⋯O hydrogen bonds, forming layers parallel to the (10[Image: see text]) plane.
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spelling pubmed-61764302018-10-12 Crystal structure of ethyl 4-[4-(di­methyl­amino)­phen­yl]-2,7,7-trimethyl-5-oxo-1,4,5,6,7,8-hexa­hydro­quinoline-3-carboxyl­ate Steiger, Scott A. Li, Chun Natale, Nicholas R. Acta Crystallogr E Crystallogr Commun Research Communications In the title racemic compound, ethyl 4-(4-di­methyl­amino­phen­yl)-2,7,7-trimethyl-5-oxo-1,4,5,6,7,8-hexa­hydro­quinoline-3-carboxyl­ate, the common structural features in this type of compound, such as the flat-boat conformation of the 1,4-di­hydro­pyridine (1,4-DHP) ring, the envelope conformation of the fused cyclo­hexa­none, and the substituted phenyl ring at the pseudo-axial position and orthogonal to the 1,4-DHP ring, are present. In the crystal, mol­ecules are linked via N—H⋯O and C—H⋯O hydrogen bonds, forming layers parallel to the (10[Image: see text]) plane. International Union of Crystallography 2018-09-11 /pmc/articles/PMC6176430/ /pubmed/30319791 http://dx.doi.org/10.1107/S2056989018011982 Text en © Steiger et al. 2018 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Steiger, Scott A.
Li, Chun
Natale, Nicholas R.
Crystal structure of ethyl 4-[4-(di­methyl­amino)­phen­yl]-2,7,7-trimethyl-5-oxo-1,4,5,6,7,8-hexa­hydro­quinoline-3-carboxyl­ate
title Crystal structure of ethyl 4-[4-(di­methyl­amino)­phen­yl]-2,7,7-trimethyl-5-oxo-1,4,5,6,7,8-hexa­hydro­quinoline-3-carboxyl­ate
title_full Crystal structure of ethyl 4-[4-(di­methyl­amino)­phen­yl]-2,7,7-trimethyl-5-oxo-1,4,5,6,7,8-hexa­hydro­quinoline-3-carboxyl­ate
title_fullStr Crystal structure of ethyl 4-[4-(di­methyl­amino)­phen­yl]-2,7,7-trimethyl-5-oxo-1,4,5,6,7,8-hexa­hydro­quinoline-3-carboxyl­ate
title_full_unstemmed Crystal structure of ethyl 4-[4-(di­methyl­amino)­phen­yl]-2,7,7-trimethyl-5-oxo-1,4,5,6,7,8-hexa­hydro­quinoline-3-carboxyl­ate
title_short Crystal structure of ethyl 4-[4-(di­methyl­amino)­phen­yl]-2,7,7-trimethyl-5-oxo-1,4,5,6,7,8-hexa­hydro­quinoline-3-carboxyl­ate
title_sort crystal structure of ethyl 4-[4-(di­methyl­amino)­phen­yl]-2,7,7-trimethyl-5-oxo-1,4,5,6,7,8-hexa­hydro­quinoline-3-carboxyl­ate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6176430/
https://www.ncbi.nlm.nih.gov/pubmed/30319791
http://dx.doi.org/10.1107/S2056989018011982
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