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Crystal structure of (E)-2-[3-(tert-but­yl)-2-hy­droxy­benzyl­idene]-N-cyclo­hexyl­hydrazine-1-carbo­thio­amide

In the title compound, C(18)H(27)N(3)OS, the cyclo­hexane ring has a chair conformation. The azomethine C=N double bond has an E configuration. The nearly planar hydrazinecarbo­thio­amide moiety and substituted benzene ring are twisted by 31.13 (5)° relative to each other. The amide moiety and the c...

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Autores principales: Arafath, Md. Azharul, Kwong, Huey Chong, Adam, Farook, Razali, Mohd. R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6176448/
https://www.ncbi.nlm.nih.gov/pubmed/30319801
http://dx.doi.org/10.1107/S2056989018013129
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author Arafath, Md. Azharul
Kwong, Huey Chong
Adam, Farook
Razali, Mohd. R.
author_facet Arafath, Md. Azharul
Kwong, Huey Chong
Adam, Farook
Razali, Mohd. R.
author_sort Arafath, Md. Azharul
collection PubMed
description In the title compound, C(18)H(27)N(3)OS, the cyclo­hexane ring has a chair conformation. The azomethine C=N double bond has an E configuration. The nearly planar hydrazinecarbo­thio­amide moiety and substituted benzene ring are twisted by 31.13 (5)° relative to each other. The amide moiety and the cyclo­hexane ring are almost perpendicular to each other; a similar conformation was previously observed in reported structures. In the crystal, mol­ecules are linked by N—H⋯S hydrogen bonds, forming inversion dimers with an R (2) (2)(8) ring motif.
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spelling pubmed-61764482018-10-12 Crystal structure of (E)-2-[3-(tert-but­yl)-2-hy­droxy­benzyl­idene]-N-cyclo­hexyl­hydrazine-1-carbo­thio­amide Arafath, Md. Azharul Kwong, Huey Chong Adam, Farook Razali, Mohd. R. Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(18)H(27)N(3)OS, the cyclo­hexane ring has a chair conformation. The azomethine C=N double bond has an E configuration. The nearly planar hydrazinecarbo­thio­amide moiety and substituted benzene ring are twisted by 31.13 (5)° relative to each other. The amide moiety and the cyclo­hexane ring are almost perpendicular to each other; a similar conformation was previously observed in reported structures. In the crystal, mol­ecules are linked by N—H⋯S hydrogen bonds, forming inversion dimers with an R (2) (2)(8) ring motif. International Union of Crystallography 2018-09-21 /pmc/articles/PMC6176448/ /pubmed/30319801 http://dx.doi.org/10.1107/S2056989018013129 Text en © Arafath et al. 2018 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Arafath, Md. Azharul
Kwong, Huey Chong
Adam, Farook
Razali, Mohd. R.
Crystal structure of (E)-2-[3-(tert-but­yl)-2-hy­droxy­benzyl­idene]-N-cyclo­hexyl­hydrazine-1-carbo­thio­amide
title Crystal structure of (E)-2-[3-(tert-but­yl)-2-hy­droxy­benzyl­idene]-N-cyclo­hexyl­hydrazine-1-carbo­thio­amide
title_full Crystal structure of (E)-2-[3-(tert-but­yl)-2-hy­droxy­benzyl­idene]-N-cyclo­hexyl­hydrazine-1-carbo­thio­amide
title_fullStr Crystal structure of (E)-2-[3-(tert-but­yl)-2-hy­droxy­benzyl­idene]-N-cyclo­hexyl­hydrazine-1-carbo­thio­amide
title_full_unstemmed Crystal structure of (E)-2-[3-(tert-but­yl)-2-hy­droxy­benzyl­idene]-N-cyclo­hexyl­hydrazine-1-carbo­thio­amide
title_short Crystal structure of (E)-2-[3-(tert-but­yl)-2-hy­droxy­benzyl­idene]-N-cyclo­hexyl­hydrazine-1-carbo­thio­amide
title_sort crystal structure of (e)-2-[3-(tert-but­yl)-2-hy­droxy­benzyl­idene]-n-cyclo­hexyl­hydrazine-1-carbo­thio­amide
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6176448/
https://www.ncbi.nlm.nih.gov/pubmed/30319801
http://dx.doi.org/10.1107/S2056989018013129
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