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Crystal structure of (E)-2-[3-(tert-butyl)-2-hydroxybenzylidene]-N-cyclohexylhydrazine-1-carbothioamide
In the title compound, C(18)H(27)N(3)OS, the cyclohexane ring has a chair conformation. The azomethine C=N double bond has an E configuration. The nearly planar hydrazinecarbothioamide moiety and substituted benzene ring are twisted by 31.13 (5)° relative to each other. The amide moiety and the c...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6176448/ https://www.ncbi.nlm.nih.gov/pubmed/30319801 http://dx.doi.org/10.1107/S2056989018013129 |
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author | Arafath, Md. Azharul Kwong, Huey Chong Adam, Farook Razali, Mohd. R. |
author_facet | Arafath, Md. Azharul Kwong, Huey Chong Adam, Farook Razali, Mohd. R. |
author_sort | Arafath, Md. Azharul |
collection | PubMed |
description | In the title compound, C(18)H(27)N(3)OS, the cyclohexane ring has a chair conformation. The azomethine C=N double bond has an E configuration. The nearly planar hydrazinecarbothioamide moiety and substituted benzene ring are twisted by 31.13 (5)° relative to each other. The amide moiety and the cyclohexane ring are almost perpendicular to each other; a similar conformation was previously observed in reported structures. In the crystal, molecules are linked by N—H⋯S hydrogen bonds, forming inversion dimers with an R (2) (2)(8) ring motif. |
format | Online Article Text |
id | pubmed-6176448 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2018 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-61764482018-10-12 Crystal structure of (E)-2-[3-(tert-butyl)-2-hydroxybenzylidene]-N-cyclohexylhydrazine-1-carbothioamide Arafath, Md. Azharul Kwong, Huey Chong Adam, Farook Razali, Mohd. R. Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(18)H(27)N(3)OS, the cyclohexane ring has a chair conformation. The azomethine C=N double bond has an E configuration. The nearly planar hydrazinecarbothioamide moiety and substituted benzene ring are twisted by 31.13 (5)° relative to each other. The amide moiety and the cyclohexane ring are almost perpendicular to each other; a similar conformation was previously observed in reported structures. In the crystal, molecules are linked by N—H⋯S hydrogen bonds, forming inversion dimers with an R (2) (2)(8) ring motif. International Union of Crystallography 2018-09-21 /pmc/articles/PMC6176448/ /pubmed/30319801 http://dx.doi.org/10.1107/S2056989018013129 Text en © Arafath et al. 2018 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/ |
spellingShingle | Research Communications Arafath, Md. Azharul Kwong, Huey Chong Adam, Farook Razali, Mohd. R. Crystal structure of (E)-2-[3-(tert-butyl)-2-hydroxybenzylidene]-N-cyclohexylhydrazine-1-carbothioamide |
title | Crystal structure of (E)-2-[3-(tert-butyl)-2-hydroxybenzylidene]-N-cyclohexylhydrazine-1-carbothioamide |
title_full | Crystal structure of (E)-2-[3-(tert-butyl)-2-hydroxybenzylidene]-N-cyclohexylhydrazine-1-carbothioamide |
title_fullStr | Crystal structure of (E)-2-[3-(tert-butyl)-2-hydroxybenzylidene]-N-cyclohexylhydrazine-1-carbothioamide |
title_full_unstemmed | Crystal structure of (E)-2-[3-(tert-butyl)-2-hydroxybenzylidene]-N-cyclohexylhydrazine-1-carbothioamide |
title_short | Crystal structure of (E)-2-[3-(tert-butyl)-2-hydroxybenzylidene]-N-cyclohexylhydrazine-1-carbothioamide |
title_sort | crystal structure of (e)-2-[3-(tert-butyl)-2-hydroxybenzylidene]-n-cyclohexylhydrazine-1-carbothioamide |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6176448/ https://www.ncbi.nlm.nih.gov/pubmed/30319801 http://dx.doi.org/10.1107/S2056989018013129 |
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