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Crystal structure and Hirshfeld surface analysis of (E)-N-[(2-ethoxynaphthalen-1-yl)methylidene]-5,6,7,8-tetrahydronaphthalen-1-amine
In the title Schiff base compound, C(23)H(23)NO, the two ring systems are twisted by 51.40 (11)° relative to each other. In the crystal, the molecules are connected by weak C—H⋯π interactions, generating a three-dimensional supramolecular structure. Hirshfeld surface analysis and two-dimensional...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6176450/ https://www.ncbi.nlm.nih.gov/pubmed/30319813 http://dx.doi.org/10.1107/S2056989018013117 |
| _version_ | 1783361705439395840 |
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| author | Kansiz, Sevgi Macit, Mustafa Dege, Necmi Tsapyuk, Galyna G. |
| author_facet | Kansiz, Sevgi Macit, Mustafa Dege, Necmi Tsapyuk, Galyna G. |
| author_sort | Kansiz, Sevgi |
| collection | PubMed |
| description | In the title Schiff base compound, C(23)H(23)NO, the two ring systems are twisted by 51.40 (11)° relative to each other. In the crystal, the molecules are connected by weak C—H⋯π interactions, generating a three-dimensional supramolecular structure. Hirshfeld surface analysis and two-dimensional fingerprint plots indicate that the most important contributions to the crystal packing are from H⋯H (67.2%), C⋯H/H⋯C (26.7%) and C⋯C (2.5%) interactions. |
| format | Online Article Text |
| id | pubmed-6176450 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2018 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-61764502018-10-12 Crystal structure and Hirshfeld surface analysis of (E)-N-[(2-ethoxynaphthalen-1-yl)methylidene]-5,6,7,8-tetrahydronaphthalen-1-amine Kansiz, Sevgi Macit, Mustafa Dege, Necmi Tsapyuk, Galyna G. Acta Crystallogr E Crystallogr Commun Research Communications In the title Schiff base compound, C(23)H(23)NO, the two ring systems are twisted by 51.40 (11)° relative to each other. In the crystal, the molecules are connected by weak C—H⋯π interactions, generating a three-dimensional supramolecular structure. Hirshfeld surface analysis and two-dimensional fingerprint plots indicate that the most important contributions to the crystal packing are from H⋯H (67.2%), C⋯H/H⋯C (26.7%) and C⋯C (2.5%) interactions. International Union of Crystallography 2018-09-28 /pmc/articles/PMC6176450/ /pubmed/30319813 http://dx.doi.org/10.1107/S2056989018013117 Text en © Kansiz et al. 2018 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/ |
| spellingShingle | Research Communications Kansiz, Sevgi Macit, Mustafa Dege, Necmi Tsapyuk, Galyna G. Crystal structure and Hirshfeld surface analysis of (E)-N-[(2-ethoxynaphthalen-1-yl)methylidene]-5,6,7,8-tetrahydronaphthalen-1-amine |
| title | Crystal structure and Hirshfeld surface analysis of (E)-N-[(2-ethoxynaphthalen-1-yl)methylidene]-5,6,7,8-tetrahydronaphthalen-1-amine |
| title_full | Crystal structure and Hirshfeld surface analysis of (E)-N-[(2-ethoxynaphthalen-1-yl)methylidene]-5,6,7,8-tetrahydronaphthalen-1-amine |
| title_fullStr | Crystal structure and Hirshfeld surface analysis of (E)-N-[(2-ethoxynaphthalen-1-yl)methylidene]-5,6,7,8-tetrahydronaphthalen-1-amine |
| title_full_unstemmed | Crystal structure and Hirshfeld surface analysis of (E)-N-[(2-ethoxynaphthalen-1-yl)methylidene]-5,6,7,8-tetrahydronaphthalen-1-amine |
| title_short | Crystal structure and Hirshfeld surface analysis of (E)-N-[(2-ethoxynaphthalen-1-yl)methylidene]-5,6,7,8-tetrahydronaphthalen-1-amine |
| title_sort | crystal structure and hirshfeld surface analysis of (e)-n-[(2-ethoxynaphthalen-1-yl)methylidene]-5,6,7,8-tetrahydronaphthalen-1-amine |
| topic | Research Communications |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6176450/ https://www.ncbi.nlm.nih.gov/pubmed/30319813 http://dx.doi.org/10.1107/S2056989018013117 |
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