Crystal structure and synthesis of 3-(1H-pyrrol-2-yl)-1-(thio­phen-2-yl)propanone

The title compound, C(11)H(9)NOS, was obtained in an improved yield compared to previous literature methods. The mol­ecule is essentially planar with a maximum deviation of 0.085 Å from the mean plane through all non-H atoms. There is directive inter­molecular hydrogen bonding in the form of N—H⋯O h...

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Detalles Bibliográficos
Autores principales: Gibbons, Dáire, Emandi, Ganapathi, Senge, Mathias O.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2018
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6176454/
https://www.ncbi.nlm.nih.gov/pubmed/30319802
http://dx.doi.org/10.1107/S2056989018012331
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author Gibbons, Dáire
Emandi, Ganapathi
Senge, Mathias O.
author_facet Gibbons, Dáire
Emandi, Ganapathi
Senge, Mathias O.
author_sort Gibbons, Dáire
collection PubMed
description The title compound, C(11)H(9)NOS, was obtained in an improved yield compared to previous literature methods. The mol­ecule is essentially planar with a maximum deviation of 0.085 Å from the mean plane through all non-H atoms. There is directive inter­molecular hydrogen bonding in the form of N—H⋯O hydrogen bonds with a distance of 2.889 (3) Å between the pyrrole amine and the ketone carbonyl O atom. The resulting hydrogen-bonding network defines a ribbon parallel to the a axis. These ribbons form offset stacks along the b axis.
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spelling pubmed-61764542018-10-12 Crystal structure and synthesis of 3-(1H-pyrrol-2-yl)-1-(thio­phen-2-yl)propanone Gibbons, Dáire Emandi, Ganapathi Senge, Mathias O. Acta Crystallogr E Crystallogr Commun Research Communications The title compound, C(11)H(9)NOS, was obtained in an improved yield compared to previous literature methods. The mol­ecule is essentially planar with a maximum deviation of 0.085 Å from the mean plane through all non-H atoms. There is directive inter­molecular hydrogen bonding in the form of N—H⋯O hydrogen bonds with a distance of 2.889 (3) Å between the pyrrole amine and the ketone carbonyl O atom. The resulting hydrogen-bonding network defines a ribbon parallel to the a axis. These ribbons form offset stacks along the b axis. International Union of Crystallography 2018-09-21 /pmc/articles/PMC6176454/ /pubmed/30319802 http://dx.doi.org/10.1107/S2056989018012331 Text en © Gibbons et al. 2018 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Gibbons, Dáire
Emandi, Ganapathi
Senge, Mathias O.
Crystal structure and synthesis of 3-(1H-pyrrol-2-yl)-1-(thio­phen-2-yl)propanone
title Crystal structure and synthesis of 3-(1H-pyrrol-2-yl)-1-(thio­phen-2-yl)propanone
title_full Crystal structure and synthesis of 3-(1H-pyrrol-2-yl)-1-(thio­phen-2-yl)propanone
title_fullStr Crystal structure and synthesis of 3-(1H-pyrrol-2-yl)-1-(thio­phen-2-yl)propanone
title_full_unstemmed Crystal structure and synthesis of 3-(1H-pyrrol-2-yl)-1-(thio­phen-2-yl)propanone
title_short Crystal structure and synthesis of 3-(1H-pyrrol-2-yl)-1-(thio­phen-2-yl)propanone
title_sort crystal structure and synthesis of 3-(1h-pyrrol-2-yl)-1-(thio­phen-2-yl)propanone
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6176454/
https://www.ncbi.nlm.nih.gov/pubmed/30319802
http://dx.doi.org/10.1107/S2056989018012331
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