Crystal structure of 3,6-dihy­droxy-4,5-di­methyl­benzene-1,2-dicarbaldehyde

The title compound, C(10)H(10)O(4), was synthesized from tetra­methyl-1,4-benzo­quinone. In the crystal, the almost planar mol­ecule (r.m.s. deviation = 0.024 Å) forms intra­molecular hydrogen bonds between the aldehyde and hy­droxy groups and exhibits C (2v) symmetry. This achiral mol­ecule crystal...

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Autores principales: Yamazaki, Shu, Nishiyama, Kazuki, Yagi, Shiomi, Haraguchi, Tomoyuki, Akitsu, Takashiro
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2018
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6176455/
https://www.ncbi.nlm.nih.gov/pubmed/30319793
http://dx.doi.org/10.1107/S2056989018012495
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author Yamazaki, Shu
Nishiyama, Kazuki
Yagi, Shiomi
Haraguchi, Tomoyuki
Akitsu, Takashiro
author_facet Yamazaki, Shu
Nishiyama, Kazuki
Yagi, Shiomi
Haraguchi, Tomoyuki
Akitsu, Takashiro
author_sort Yamazaki, Shu
collection PubMed
description The title compound, C(10)H(10)O(4), was synthesized from tetra­methyl-1,4-benzo­quinone. In the crystal, the almost planar mol­ecule (r.m.s. deviation = 0.024 Å) forms intra­molecular hydrogen bonds between the aldehyde and hy­droxy groups and exhibits C (2v) symmetry. This achiral mol­ecule crystallizes in the chiral space group P2(1) with inter­molecular O—H⋯O and C—H⋯O hydrogen bonding and C—H⋯π and C=O⋯π inter­actions stabilizing the crystal packing.
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spelling pubmed-61764552018-10-12 Crystal structure of 3,6-dihy­droxy-4,5-di­methyl­benzene-1,2-dicarbaldehyde Yamazaki, Shu Nishiyama, Kazuki Yagi, Shiomi Haraguchi, Tomoyuki Akitsu, Takashiro Acta Crystallogr E Crystallogr Commun Research Communications The title compound, C(10)H(10)O(4), was synthesized from tetra­methyl-1,4-benzo­quinone. In the crystal, the almost planar mol­ecule (r.m.s. deviation = 0.024 Å) forms intra­molecular hydrogen bonds between the aldehyde and hy­droxy groups and exhibits C (2v) symmetry. This achiral mol­ecule crystallizes in the chiral space group P2(1) with inter­molecular O—H⋯O and C—H⋯O hydrogen bonding and C—H⋯π and C=O⋯π inter­actions stabilizing the crystal packing. International Union of Crystallography 2018-09-14 /pmc/articles/PMC6176455/ /pubmed/30319793 http://dx.doi.org/10.1107/S2056989018012495 Text en © Yamazaki et al. 2018 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Yamazaki, Shu
Nishiyama, Kazuki
Yagi, Shiomi
Haraguchi, Tomoyuki
Akitsu, Takashiro
Crystal structure of 3,6-dihy­droxy-4,5-di­methyl­benzene-1,2-dicarbaldehyde
title Crystal structure of 3,6-dihy­droxy-4,5-di­methyl­benzene-1,2-dicarbaldehyde
title_full Crystal structure of 3,6-dihy­droxy-4,5-di­methyl­benzene-1,2-dicarbaldehyde
title_fullStr Crystal structure of 3,6-dihy­droxy-4,5-di­methyl­benzene-1,2-dicarbaldehyde
title_full_unstemmed Crystal structure of 3,6-dihy­droxy-4,5-di­methyl­benzene-1,2-dicarbaldehyde
title_short Crystal structure of 3,6-dihy­droxy-4,5-di­methyl­benzene-1,2-dicarbaldehyde
title_sort crystal structure of 3,6-dihy­droxy-4,5-di­methyl­benzene-1,2-dicarbaldehyde
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6176455/
https://www.ncbi.nlm.nih.gov/pubmed/30319793
http://dx.doi.org/10.1107/S2056989018012495
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