Synergistic approach to polycycles through Suzuki–Miyaura cross coupling and metathesis as key steps

This account provides an overview of recent work, including our own contribution dealing with Suzuki–Miyaura cross coupling in combination with metathesis (or vice-versa). Several cyclophanes, polycycles, macrocycles, spirocycles, stilbenes, biaryls, and heterocycles have been synthesized by employi...

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Autores principales: Kotha, Sambasivarao, Meshram, Milind, Chakkapalli, Chandravathi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2018
Materias:
Review
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6176834/
https://www.ncbi.nlm.nih.gov/pubmed/30344770
http://dx.doi.org/10.3762/bjoc.14.223
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author Kotha, Sambasivarao
Meshram, Milind
Chakkapalli, Chandravathi
author_facet Kotha, Sambasivarao
Meshram, Milind
Chakkapalli, Chandravathi
author_sort Kotha, Sambasivarao
collection PubMed
description This account provides an overview of recent work, including our own contribution dealing with Suzuki–Miyaura cross coupling in combination with metathesis (or vice-versa). Several cyclophanes, polycycles, macrocycles, spirocycles, stilbenes, biaryls, and heterocycles have been synthesized by employing a combination of Suzuki cross-coupling and metathesis. Various popular reactions such as Diels–Alder reaction, Claisen rearrangement, cross-metathesis, and cross-enyne metathesis are used. The synergistic combination of these powerful reactions is found to be useful for the construction of complex targets and fulfill synthetic brevity.
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spelling pubmed-61768342018-10-19 Synergistic approach to polycycles through Suzuki–Miyaura cross coupling and metathesis as key steps Kotha, Sambasivarao Meshram, Milind Chakkapalli, Chandravathi Beilstein J Org Chem Review This account provides an overview of recent work, including our own contribution dealing with Suzuki–Miyaura cross coupling in combination with metathesis (or vice-versa). Several cyclophanes, polycycles, macrocycles, spirocycles, stilbenes, biaryls, and heterocycles have been synthesized by employing a combination of Suzuki cross-coupling and metathesis. Various popular reactions such as Diels–Alder reaction, Claisen rearrangement, cross-metathesis, and cross-enyne metathesis are used. The synergistic combination of these powerful reactions is found to be useful for the construction of complex targets and fulfill synthetic brevity. Beilstein-Institut 2018-09-21 /pmc/articles/PMC6176834/ /pubmed/30344770 http://dx.doi.org/10.3762/bjoc.14.223 Text en Copyright © 2018, Kotha et al. https://creativecommons.org/licenses/by/4.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/4.0). Please note that the reuse, redistribution and reproduction in particular requires that the authors and source are credited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Review
Kotha, Sambasivarao
Meshram, Milind
Chakkapalli, Chandravathi
Synergistic approach to polycycles through Suzuki–Miyaura cross coupling and metathesis as key steps
title Synergistic approach to polycycles through Suzuki–Miyaura cross coupling and metathesis as key steps
title_full Synergistic approach to polycycles through Suzuki–Miyaura cross coupling and metathesis as key steps
title_fullStr Synergistic approach to polycycles through Suzuki–Miyaura cross coupling and metathesis as key steps
title_full_unstemmed Synergistic approach to polycycles through Suzuki–Miyaura cross coupling and metathesis as key steps
title_short Synergistic approach to polycycles through Suzuki–Miyaura cross coupling and metathesis as key steps
title_sort synergistic approach to polycycles through suzuki–miyaura cross coupling and metathesis as key steps
topic Review
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6176834/
https://www.ncbi.nlm.nih.gov/pubmed/30344770
http://dx.doi.org/10.3762/bjoc.14.223
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AT chakkapallichandravathi synergisticapproachtopolycyclesthroughsuzukimiyauracrosscouplingandmetathesisaskeysteps

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