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Hierarchical tandem assembly of planar [3×3] building units into {3×[3×3]} oligomers: mixed-valency, electrical conductivity and magnetism
A hierarchical tandem assembly – coordination, oligomerisation and supramolecular organization – is identified using MALDI-TOF of the solid products of the solvothermal reaction of 5,5′-pyridyl-3,3′-bi-1H-pyrazole with CuSO(4)·5H(2)O in CH(3)OH–CH(3)CN. The initial coordination leads to a [3×3] [CuI...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6176900/ https://www.ncbi.nlm.nih.gov/pubmed/30319749 http://dx.doi.org/10.1039/c8sc02851f |