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Chiral Aniline Synthesis via Stereospecific C(sp(3))–C(sp(2)) Coupling of Boronic Esters with Aryl Hydrazines

[Image: see text] An enantiospecific coupling between alkylboronic esters and lithiated aryl hydrazines is described. The reaction proceeds under transition-metal-free conditions and is promoted by acylation of a hydrazinyl arylboronate complex, which triggers a N–N bond cleavage with concomitant 1,...

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Detalles Bibliográficos
Autores principales:	Ganesh, Venkataraman, Noble, Adam, Aggarwal, Varinder K.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2018
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6178205/ https://www.ncbi.nlm.nih.gov/pubmed/30221524 http://dx.doi.org/10.1021/acs.orglett.8b02615

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