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Dihydrogen contacts observed by through-space indirect NMR coupling
“Through-space” indirect spin–spin couplings between hydrogen atoms formally separated by up to 18 covalent bonds have been detected by NMR experiments in model helical molecules. It is demonstrated that this coupling can provide crucial structural information on the molecular conformation in soluti...
Autores principales: | Dračínský, Martin, Buchta, Michal, Buděšínský, Miloš, Vacek-Chocholoušová, Jana, Stará, Irena G., Starý, Ivo, Malkina, Olga L. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6180313/ https://www.ncbi.nlm.nih.gov/pubmed/30319744 http://dx.doi.org/10.1039/c8sc02859a |
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