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A β-diketiminate manganese catalyst for alkene hydrosilylation: substrate scope, silicone preparation, and mechanistic insight
The dimeric β-diketiminate manganese hydride compound, [((2,6-iPr2Ph)BDI)Mn(μ-H)](2), was prepared by treating [((2,6-iPr2Ph)BDI)Mn(μ-Cl)](2) with NaEt(3)BH. This compound was characterized by single crystal X-ray diffraction and found to feature high-spin Mn centres that exhibit strong magnetic cou...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6182418/ https://www.ncbi.nlm.nih.gov/pubmed/30393528 http://dx.doi.org/10.1039/c8sc02768d |