Four-coordinate triarylborane synthesis via cascade B–Cl/C–B cross-metathesis and C–H bond borylation

To develop a simple and efficient synthetic method for four-coordinate triarylboranes, we herein describe a tandem highly selective B–Cl/C–B cross-metathesis of two of the same or different arylboranes and C–H bond borylation to synthesize four-coordinate triarylboranes with a broad substrate scope....

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Detalles Bibliográficos
Autores principales: Yang, Kai, Zhang, Guan, Song, Qiuling
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6182419/
https://www.ncbi.nlm.nih.gov/pubmed/30393527
http://dx.doi.org/10.1039/c8sc02281j
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author Yang, Kai
Zhang, Guan
Song, Qiuling
author_facet Yang, Kai
Zhang, Guan
Song, Qiuling
author_sort Yang, Kai
collection PubMed
description To develop a simple and efficient synthetic method for four-coordinate triarylboranes, we herein describe a tandem highly selective B–Cl/C–B cross-metathesis of two of the same or different arylboranes and C–H bond borylation to synthesize four-coordinate triarylboranes with a broad substrate scope. By switching substituent groups of the target molecules, different emission wavelengths can be achieved from 467 nm to 583 nm with aggregation-induced emission (AIE) properties.
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spelling pubmed-61824192018-11-02 Four-coordinate triarylborane synthesis via cascade B–Cl/C–B cross-metathesis and C–H bond borylation Yang, Kai Zhang, Guan Song, Qiuling Chem Sci Chemistry To develop a simple and efficient synthetic method for four-coordinate triarylboranes, we herein describe a tandem highly selective B–Cl/C–B cross-metathesis of two of the same or different arylboranes and C–H bond borylation to synthesize four-coordinate triarylboranes with a broad substrate scope. By switching substituent groups of the target molecules, different emission wavelengths can be achieved from 467 nm to 583 nm with aggregation-induced emission (AIE) properties. Royal Society of Chemistry 2018-08-13 /pmc/articles/PMC6182419/ /pubmed/30393527 http://dx.doi.org/10.1039/c8sc02281j Text en This journal is © The Royal Society of Chemistry 2018 http://creativecommons.org/licenses/by/3.0/ This article is freely available. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence (CC BY 3.0)
spellingShingle Chemistry
Yang, Kai
Zhang, Guan
Song, Qiuling
Four-coordinate triarylborane synthesis via cascade B–Cl/C–B cross-metathesis and C–H bond borylation
title Four-coordinate triarylborane synthesis via cascade B–Cl/C–B cross-metathesis and C–H bond borylation
title_full Four-coordinate triarylborane synthesis via cascade B–Cl/C–B cross-metathesis and C–H bond borylation
title_fullStr Four-coordinate triarylborane synthesis via cascade B–Cl/C–B cross-metathesis and C–H bond borylation
title_full_unstemmed Four-coordinate triarylborane synthesis via cascade B–Cl/C–B cross-metathesis and C–H bond borylation
title_short Four-coordinate triarylborane synthesis via cascade B–Cl/C–B cross-metathesis and C–H bond borylation
title_sort four-coordinate triarylborane synthesis via cascade b–cl/c–b cross-metathesis and c–h bond borylation
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6182419/
https://www.ncbi.nlm.nih.gov/pubmed/30393527
http://dx.doi.org/10.1039/c8sc02281j
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AT zhangguan fourcoordinatetriarylboranesynthesisviacascadebclcbcrossmetathesisandchbondborylation
AT songqiuling fourcoordinatetriarylboranesynthesisviacascadebclcbcrossmetathesisandchbondborylation

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