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Wetting of soft superhydrophobic micropillar arrays

Superhydrophobic surfaces are usually assumed to be rigid so that liquids do not deform them. Here we analyze how the relation between microstructure and wetting changes when the surface is flexible. Therefore we deposited liquid drops on arrays of flexible micropillars. We imaged the drop's su...

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Detalles Bibliográficos
Autores principales: Papadopoulos, Periklis, Pinchasik, Bat-El, Tress, Martin, Vollmer, Doris, Kappl, Michael, Butt, Hans-Jürgen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6192145/
https://www.ncbi.nlm.nih.gov/pubmed/30183043
http://dx.doi.org/10.1039/c8sm01333k
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author Papadopoulos, Periklis
Pinchasik, Bat-El
Tress, Martin
Vollmer, Doris
Kappl, Michael
Butt, Hans-Jürgen
author_facet Papadopoulos, Periklis
Pinchasik, Bat-El
Tress, Martin
Vollmer, Doris
Kappl, Michael
Butt, Hans-Jürgen
author_sort Papadopoulos, Periklis
collection PubMed
description Superhydrophobic surfaces are usually assumed to be rigid so that liquids do not deform them. Here we analyze how the relation between microstructure and wetting changes when the surface is flexible. Therefore we deposited liquid drops on arrays of flexible micropillars. We imaged the drop's surface and the bending of micropillars with confocal microscopy and analyzed the deflection of micropillars while the contact line advanced and receded. The deflection is directly proportional to the horizontal component of the capillary force acting on that particular micropillar. In the Cassie or “fakir” state, drops advance by touching down on the next top faces of micropillars, much like on rigid arrays. In contrast, on the receding side the micropillars deform. The main force hindering the slide of a drop is due to pinning at the receding side, while the force on the advancing side is negligible. In the Wenzel state, micropillars were deflected in both receding and advancing states.
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spelling pubmed-61921452018-11-02 Wetting of soft superhydrophobic micropillar arrays Papadopoulos, Periklis Pinchasik, Bat-El Tress, Martin Vollmer, Doris Kappl, Michael Butt, Hans-Jürgen Soft Matter Chemistry Superhydrophobic surfaces are usually assumed to be rigid so that liquids do not deform them. Here we analyze how the relation between microstructure and wetting changes when the surface is flexible. Therefore we deposited liquid drops on arrays of flexible micropillars. We imaged the drop's surface and the bending of micropillars with confocal microscopy and analyzed the deflection of micropillars while the contact line advanced and receded. The deflection is directly proportional to the horizontal component of the capillary force acting on that particular micropillar. In the Cassie or “fakir” state, drops advance by touching down on the next top faces of micropillars, much like on rigid arrays. In contrast, on the receding side the micropillars deform. The main force hindering the slide of a drop is due to pinning at the receding side, while the force on the advancing side is negligible. In the Wenzel state, micropillars were deflected in both receding and advancing states. Royal Society of Chemistry 2018-09-28 2018-09-05 /pmc/articles/PMC6192145/ /pubmed/30183043 http://dx.doi.org/10.1039/c8sm01333k Text en This journal is © The Royal Society of Chemistry 2018 http://creativecommons.org/licenses/by/3.0/ This article is freely available. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence (CC BY 3.0)
spellingShingle Chemistry
Papadopoulos, Periklis
Pinchasik, Bat-El
Tress, Martin
Vollmer, Doris
Kappl, Michael
Butt, Hans-Jürgen
Wetting of soft superhydrophobic micropillar arrays
title Wetting of soft superhydrophobic micropillar arrays
title_full Wetting of soft superhydrophobic micropillar arrays
title_fullStr Wetting of soft superhydrophobic micropillar arrays
title_full_unstemmed Wetting of soft superhydrophobic micropillar arrays
title_short Wetting of soft superhydrophobic micropillar arrays
title_sort wetting of soft superhydrophobic micropillar arrays
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6192145/
https://www.ncbi.nlm.nih.gov/pubmed/30183043
http://dx.doi.org/10.1039/c8sm01333k
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