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Synthesis of a Cyclic Co(2)Sn(2) Cluster Using a Co(–) Synthon
[Image: see text] [Ar′SnCo](2) (1, Ar′ = C(6)H(3)-2,6{C(6)H(3)-2,6-(i)Pr(2)}(2)), a rare metal–metal bonded cobalt–tin cluster with low-coordinate tin atoms, was prepared by the reaction of [K(thf)(0.2)][Co(1,5-cod)(2)] (cod = 1,5-cyclooctadiene) with [Ar′Sn(μ-Cl)](2). This reaction illustrates a pr...
| Autores principales: | , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2018
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6194648/ https://www.ncbi.nlm.nih.gov/pubmed/30269488 http://dx.doi.org/10.1021/jacs.8b08517 |
| _version_ | 1783364268572278784 |
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| author | Hoidn, Christian M. Rödl, Christian McCrea-Hendrick, Madison L. Block, Theresa Pöttgen, Rainer Ehlers, Andreas W. Power, Philip P. Wolf, Robert |
| author_facet | Hoidn, Christian M. Rödl, Christian McCrea-Hendrick, Madison L. Block, Theresa Pöttgen, Rainer Ehlers, Andreas W. Power, Philip P. Wolf, Robert |
| author_sort | Hoidn, Christian M. |
| collection | PubMed |
| description | [Image: see text] [Ar′SnCo](2) (1, Ar′ = C(6)H(3)-2,6{C(6)H(3)-2,6-(i)Pr(2)}(2)), a rare metal–metal bonded cobalt–tin cluster with low-coordinate tin atoms, was prepared by the reaction of [K(thf)(0.2)][Co(1,5-cod)(2)] (cod = 1,5-cyclooctadiene) with [Ar′Sn(μ-Cl)](2). This reaction illustrates a promising synthetic strategy to access uncommon metal clusters. The structure of 1 features a rhomboidal Co(2)Sn(2) core with strong metal–metal bonds between tin and cobalt and a weaker tin–tin interaction. Reaction of 1 with white phosphorus afforded [Ar′(2)Sn(2)Co(2)P(4)] (2), the first molecular cluster compound containing phosphorus, cobalt and tin. |
| format | Online Article Text |
| id | pubmed-6194648 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2018 |
| publisher | American Chemical
Society |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-61946482018-10-20 Synthesis of a Cyclic Co(2)Sn(2) Cluster Using a Co(–) Synthon Hoidn, Christian M. Rödl, Christian McCrea-Hendrick, Madison L. Block, Theresa Pöttgen, Rainer Ehlers, Andreas W. Power, Philip P. Wolf, Robert J Am Chem Soc [Image: see text] [Ar′SnCo](2) (1, Ar′ = C(6)H(3)-2,6{C(6)H(3)-2,6-(i)Pr(2)}(2)), a rare metal–metal bonded cobalt–tin cluster with low-coordinate tin atoms, was prepared by the reaction of [K(thf)(0.2)][Co(1,5-cod)(2)] (cod = 1,5-cyclooctadiene) with [Ar′Sn(μ-Cl)](2). This reaction illustrates a promising synthetic strategy to access uncommon metal clusters. The structure of 1 features a rhomboidal Co(2)Sn(2) core with strong metal–metal bonds between tin and cobalt and a weaker tin–tin interaction. Reaction of 1 with white phosphorus afforded [Ar′(2)Sn(2)Co(2)P(4)] (2), the first molecular cluster compound containing phosphorus, cobalt and tin. American Chemical Society 2018-10-01 2018-10-17 /pmc/articles/PMC6194648/ /pubmed/30269488 http://dx.doi.org/10.1021/jacs.8b08517 Text en Copyright © 2018 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes. |
| spellingShingle | Hoidn, Christian M. Rödl, Christian McCrea-Hendrick, Madison L. Block, Theresa Pöttgen, Rainer Ehlers, Andreas W. Power, Philip P. Wolf, Robert Synthesis of a Cyclic Co(2)Sn(2) Cluster Using a Co(–) Synthon |
| title | Synthesis
of a Cyclic Co(2)Sn(2) Cluster Using a Co(–) Synthon |
| title_full | Synthesis
of a Cyclic Co(2)Sn(2) Cluster Using a Co(–) Synthon |
| title_fullStr | Synthesis
of a Cyclic Co(2)Sn(2) Cluster Using a Co(–) Synthon |
| title_full_unstemmed | Synthesis
of a Cyclic Co(2)Sn(2) Cluster Using a Co(–) Synthon |
| title_short | Synthesis
of a Cyclic Co(2)Sn(2) Cluster Using a Co(–) Synthon |
| title_sort | synthesis
of a cyclic co(2)sn(2) cluster using a co(–) synthon |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6194648/ https://www.ncbi.nlm.nih.gov/pubmed/30269488 http://dx.doi.org/10.1021/jacs.8b08517 |
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