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Synthesis of a Cyclic Co(2)Sn(2) Cluster Using a Co(–) Synthon

[Image: see text] [Ar′SnCo](2) (1, Ar′ = C(6)H(3)-2,6{C(6)H(3)-2,6-(i)Pr(2)}(2)), a rare metal–metal bonded cobalt–tin cluster with low-coordinate tin atoms, was prepared by the reaction of [K(thf)(0.2)][Co(1,5-cod)(2)] (cod = 1,5-cyclooctadiene) with [Ar′Sn(μ-Cl)](2). This reaction illustrates a pr...

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Detalles Bibliográficos
Autores principales: Hoidn, Christian M., Rödl, Christian, McCrea-Hendrick, Madison L., Block, Theresa, Pöttgen, Rainer, Ehlers, Andreas W., Power, Philip P., Wolf, Robert
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6194648/
https://www.ncbi.nlm.nih.gov/pubmed/30269488
http://dx.doi.org/10.1021/jacs.8b08517