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Synthesis of a Cyclic Co(2)Sn(2) Cluster Using a Co(–) Synthon
[Image: see text] [Ar′SnCo](2) (1, Ar′ = C(6)H(3)-2,6{C(6)H(3)-2,6-(i)Pr(2)}(2)), a rare metal–metal bonded cobalt–tin cluster with low-coordinate tin atoms, was prepared by the reaction of [K(thf)(0.2)][Co(1,5-cod)(2)] (cod = 1,5-cyclooctadiene) with [Ar′Sn(μ-Cl)](2). This reaction illustrates a pr...
| Autores principales: | , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2018
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6194648/ https://www.ncbi.nlm.nih.gov/pubmed/30269488 http://dx.doi.org/10.1021/jacs.8b08517 |