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Shedding Light on the Protonation States and Location of Protonated N Atoms of Adenine in Metal–Organic Frameworks

[Image: see text] We report the syntheses and structures of five metal–organic frameworks (MOFs) based on transition metals (Ni(II), Cu(II), and Zn(II)), adenine, and di-, tri-, and tetra-carboxylate ligands. Adenine, with multiple N donor sites, was found to coordinate to the metal centers in diffe...

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Detalles Bibliográficos
Autores principales: Gładysiak, Andrzej, Nguyen, Tu N., Anderson, Samantha L., Boyd, Peter G., Palgrave, Robert G., Bacsa, John, Smit, Berend, Rosseinsky, Matthew J., Stylianou, Kyriakos C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6194650/
https://www.ncbi.nlm.nih.gov/pubmed/29389124
http://dx.doi.org/10.1021/acs.inorgchem.7b02761