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Unravelling interrelations between chemical composition and refractive index dispersion of infrared-transmitting chalcogenide glasses
A facile procedure for compositional screening of chalcogenide glass (CG) is proposed to manage its infrared transmission edge (ω(c)) as well as refractive index dispersion (ν) in the long-wavelength infrared (LWIR) range. Both ω(c) and ν of CG turn out to be interpretable simply in connection with...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6195534/ https://www.ncbi.nlm.nih.gov/pubmed/30341331 http://dx.doi.org/10.1038/s41598-018-33824-x |
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author | Lee, Jun Ho Choi, Ju Hyeon Yi, Jeong Han Lee, Woo Hyung Lee, Eui Sam Choi, Yong Gyu |
author_facet | Lee, Jun Ho Choi, Ju Hyeon Yi, Jeong Han Lee, Woo Hyung Lee, Eui Sam Choi, Yong Gyu |
author_sort | Lee, Jun Ho |
collection | PubMed |
description | A facile procedure for compositional screening of chalcogenide glass (CG) is proposed to manage its infrared transmission edge (ω(c)) as well as refractive index dispersion (ν) in the long-wavelength infrared (LWIR) range. Both ω(c) and ν of CG turn out to be interpretable simply in connection with its chemical composition based on a postulation that CG behaves as a single average harmonic oscillator (SAHO). In this SAHO model, ω(c) is expressed as a function of molar mass and average bond energy, both of which are easily accessible for a given CG composition. Two prototypical CG-forming systems in Ge-Sb-Se and Ge-Sb-S compositions exemplify the empirical compositional dependence of ω(c), which further plays a decisive role in determining ν. Following the present approach, a set of highly dispersive CG compositions in the Ge-Sb-S system is newly unveiled together with low-dispersion Ge-Sb-Se glasses. It is then experimentally demonstrated that a doublet lens configuration consisting of convex and concave lenses with low and high ν values, respectively, is able to reduce the optical aberrations. This finding presents an opportunity that ν can be envisaged just based on the compositional ratio of CG, thus facilitating completion of the LWIR Abbe diagram. |
format | Online Article Text |
id | pubmed-6195534 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2018 |
publisher | Nature Publishing Group UK |
record_format | MEDLINE/PubMed |
spelling | pubmed-61955342018-10-24 Unravelling interrelations between chemical composition and refractive index dispersion of infrared-transmitting chalcogenide glasses Lee, Jun Ho Choi, Ju Hyeon Yi, Jeong Han Lee, Woo Hyung Lee, Eui Sam Choi, Yong Gyu Sci Rep Article A facile procedure for compositional screening of chalcogenide glass (CG) is proposed to manage its infrared transmission edge (ω(c)) as well as refractive index dispersion (ν) in the long-wavelength infrared (LWIR) range. Both ω(c) and ν of CG turn out to be interpretable simply in connection with its chemical composition based on a postulation that CG behaves as a single average harmonic oscillator (SAHO). In this SAHO model, ω(c) is expressed as a function of molar mass and average bond energy, both of which are easily accessible for a given CG composition. Two prototypical CG-forming systems in Ge-Sb-Se and Ge-Sb-S compositions exemplify the empirical compositional dependence of ω(c), which further plays a decisive role in determining ν. Following the present approach, a set of highly dispersive CG compositions in the Ge-Sb-S system is newly unveiled together with low-dispersion Ge-Sb-Se glasses. It is then experimentally demonstrated that a doublet lens configuration consisting of convex and concave lenses with low and high ν values, respectively, is able to reduce the optical aberrations. This finding presents an opportunity that ν can be envisaged just based on the compositional ratio of CG, thus facilitating completion of the LWIR Abbe diagram. Nature Publishing Group UK 2018-10-19 /pmc/articles/PMC6195534/ /pubmed/30341331 http://dx.doi.org/10.1038/s41598-018-33824-x Text en © The Author(s) 2018 Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/. |
spellingShingle | Article Lee, Jun Ho Choi, Ju Hyeon Yi, Jeong Han Lee, Woo Hyung Lee, Eui Sam Choi, Yong Gyu Unravelling interrelations between chemical composition and refractive index dispersion of infrared-transmitting chalcogenide glasses |
title | Unravelling interrelations between chemical composition and refractive index dispersion of infrared-transmitting chalcogenide glasses |
title_full | Unravelling interrelations between chemical composition and refractive index dispersion of infrared-transmitting chalcogenide glasses |
title_fullStr | Unravelling interrelations between chemical composition and refractive index dispersion of infrared-transmitting chalcogenide glasses |
title_full_unstemmed | Unravelling interrelations between chemical composition and refractive index dispersion of infrared-transmitting chalcogenide glasses |
title_short | Unravelling interrelations between chemical composition and refractive index dispersion of infrared-transmitting chalcogenide glasses |
title_sort | unravelling interrelations between chemical composition and refractive index dispersion of infrared-transmitting chalcogenide glasses |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6195534/ https://www.ncbi.nlm.nih.gov/pubmed/30341331 http://dx.doi.org/10.1038/s41598-018-33824-x |
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