BiVO(4) Photoanode with Exposed (040) Facets for Enhanced Photoelectrochemical Performance

A BiVO(4) photoanode with exposed (040) facets was prepared to enhance its photoelectrochemical performance. The exposure of the (040) crystal planes of the BiVO(4) film was induced by adding NaCl to the precursor solution. The as-prepared BiVO(4) photoanode exhibits higher solar-light absorption and charge-separation efficiency compared to those of an anode prepared without adding NaCl. To our knowledge, the photocurrent density (1.26 mA cm(−2) at 1.23 V vs. RHE) of as-prepared BiVO(4) photoanode is the highest according to the reports for bare BiVO(4) films under simulated AM1.5G solar light, and the incident photon-to-current conversion efficiency is above 35% at 400 nm. The photoelectrochemical (PEC) water-splitting performance was also dramatically improved with a hydrogen evolution rate of 9.11 μmol cm(−2) h(−1), which is five times compared with the BiVO(4) photoanode prepared without NaCl (1.82 μmol cm(−2) h(−1)). Intensity-modulated photocurrent spectroscopy and transient photocurrent measurements show a higher charge-carrier-transfer rate for this photoanode. These results demonstrate a promising approach for the development of high-performance BiVO(4) photoanodes which can be used for efficient PEC water splitting and degradation of organic pollutants. [Image: see text] ELECTRONIC SUPPLEMENTARY MATERIAL: The online version of this article (doi:10.1007/s40820-017-0163-3) contains supplementary material, which is available to authorized users.