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Synthesis and Characterization of Graphene/ITO Nanoparticle Hybrid Transparent Conducting Electrode
The combination of graphene with conductive nanoparticles, forming graphene–nanoparticle hybrid materials, offers a number of excellent properties for advanced engineering applications. A novel and simple method was developed to deposit 10 wt% tin-doped indium tin oxide (ITO) nanoparticles on graphe...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Springer Berlin Heidelberg
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6199067/ https://www.ncbi.nlm.nih.gov/pubmed/30393667 http://dx.doi.org/10.1007/s40820-017-0174-0 |
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author | Hemasiri, Bastian Waduge Naveen Harindu Kim, Jae-Kwan Lee, Ji-Myon |
author_facet | Hemasiri, Bastian Waduge Naveen Harindu Kim, Jae-Kwan Lee, Ji-Myon |
author_sort | Hemasiri, Bastian Waduge Naveen Harindu |
collection | PubMed |
description | The combination of graphene with conductive nanoparticles, forming graphene–nanoparticle hybrid materials, offers a number of excellent properties for advanced engineering applications. A novel and simple method was developed to deposit 10 wt% tin-doped indium tin oxide (ITO) nanoparticles on graphene. The method involved a combination of a solution-based environmentally friendly electroless deposition approach and subsequent vacuum annealing. A stable organic-free solution of ITO was prepared from economical salts of In(NO(3))(3)(·)H(2)O and SnCl(4). The obtained ITO nanostructure exhibited a unique architecture, with uniformly dispersed 25–35 nm size ITO nanoparticles, containing only the crystallized In(2)O(3) phase. The synthesized ITO nanoparticles–graphene hybrid exhibited very good and reproducible optical transparency in the visible range (more than 85%) and a 28.2% improvement in electrical conductivity relative to graphene synthesized by chemical vapor deposition. It was observed that the ITO nanoparticles affect the position of the Raman signal of graphene, in which the D, G, and 2D peaks were redshifted by 5.65, 5.69, and 9.74 cm(−1), respectively, and the annealing conditions had no significant effect on the Raman signatures of graphene. [Image: see text] |
format | Online Article Text |
id | pubmed-6199067 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2017 |
publisher | Springer Berlin Heidelberg |
record_format | MEDLINE/PubMed |
spelling | pubmed-61990672018-11-02 Synthesis and Characterization of Graphene/ITO Nanoparticle Hybrid Transparent Conducting Electrode Hemasiri, Bastian Waduge Naveen Harindu Kim, Jae-Kwan Lee, Ji-Myon Nanomicro Lett Article The combination of graphene with conductive nanoparticles, forming graphene–nanoparticle hybrid materials, offers a number of excellent properties for advanced engineering applications. A novel and simple method was developed to deposit 10 wt% tin-doped indium tin oxide (ITO) nanoparticles on graphene. The method involved a combination of a solution-based environmentally friendly electroless deposition approach and subsequent vacuum annealing. A stable organic-free solution of ITO was prepared from economical salts of In(NO(3))(3)(·)H(2)O and SnCl(4). The obtained ITO nanostructure exhibited a unique architecture, with uniformly dispersed 25–35 nm size ITO nanoparticles, containing only the crystallized In(2)O(3) phase. The synthesized ITO nanoparticles–graphene hybrid exhibited very good and reproducible optical transparency in the visible range (more than 85%) and a 28.2% improvement in electrical conductivity relative to graphene synthesized by chemical vapor deposition. It was observed that the ITO nanoparticles affect the position of the Raman signal of graphene, in which the D, G, and 2D peaks were redshifted by 5.65, 5.69, and 9.74 cm(−1), respectively, and the annealing conditions had no significant effect on the Raman signatures of graphene. [Image: see text] Springer Berlin Heidelberg 2017-11-28 /pmc/articles/PMC6199067/ /pubmed/30393667 http://dx.doi.org/10.1007/s40820-017-0174-0 Text en © The Author(s) 2017 Open AccessThis article is distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. |
spellingShingle | Article Hemasiri, Bastian Waduge Naveen Harindu Kim, Jae-Kwan Lee, Ji-Myon Synthesis and Characterization of Graphene/ITO Nanoparticle Hybrid Transparent Conducting Electrode |
title | Synthesis and Characterization of Graphene/ITO Nanoparticle Hybrid Transparent Conducting Electrode |
title_full | Synthesis and Characterization of Graphene/ITO Nanoparticle Hybrid Transparent Conducting Electrode |
title_fullStr | Synthesis and Characterization of Graphene/ITO Nanoparticle Hybrid Transparent Conducting Electrode |
title_full_unstemmed | Synthesis and Characterization of Graphene/ITO Nanoparticle Hybrid Transparent Conducting Electrode |
title_short | Synthesis and Characterization of Graphene/ITO Nanoparticle Hybrid Transparent Conducting Electrode |
title_sort | synthesis and characterization of graphene/ito nanoparticle hybrid transparent conducting electrode |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6199067/ https://www.ncbi.nlm.nih.gov/pubmed/30393667 http://dx.doi.org/10.1007/s40820-017-0174-0 |
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