The special role of B(C(6)F(5))(3) in the single electron reduction of quinones by radicals

In the presence of two molar equiv. of B(C(6)F(5))(3)p-benzoquinone reacts with persistent radicals TEMPO, trityl or decamethylferrocene by single electron transfer to give doubly O-borylated benzosemiquinone radical anions with TEMPO(+), trityl or [Image: see text] ferrocenium counter cations. All...

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Detalles Bibliográficos
Autores principales: Tao, Xin, Daniliuc, Constantin G., Knitsch, Robert, Hansen, Michael Ryan, Eckert, Hellmut, Lübbesmeyer, Maximilian, Studer, Armido, Kehr, Gerald, Erker, Gerhard
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6202917/
https://www.ncbi.nlm.nih.gov/pubmed/30450185
http://dx.doi.org/10.1039/c8sc03005g

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6202917/
https://www.ncbi.nlm.nih.gov/pubmed/30450185
http://dx.doi.org/10.1039/c8sc03005g

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