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The special role of B(C(6)F(5))(3) in the single electron reduction of quinones by radicals
In the presence of two molar equiv. of B(C(6)F(5))(3)p-benzoquinone reacts with persistent radicals TEMPO, trityl or decamethylferrocene by single electron transfer to give doubly O-borylated benzosemiquinone radical anions with TEMPO(+), trityl or [Image: see text] ferrocenium counter cations. All...
| Autores principales: | , , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6202917/ https://www.ncbi.nlm.nih.gov/pubmed/30450185 http://dx.doi.org/10.1039/c8sc03005g |