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Transition metal-free oxidative and deoxygenative C–H/C–Li cross-couplings of 2H-imidazole 1-oxides with carboranyl lithium as an efficient synthetic approach to azaheterocyclic carboranes

The direct C–H functionalization methodology has first been applied to perform transition metal-free C–H/C–Li cross-couplings of 2H-imidazole 1-oxides with carboranyllithium. This atom- and step-economical approach, based on one-pot reactions of nucleophilic substitution of hydrogen (S(N)(H)) in non...

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Detalles Bibliográficos
Autores principales:	Smyshliaeva, Lidia A, Varaksin, Mikhail V, Slepukhin, Pavel A, Chupakhin, Oleg N, Charushin, Valery N
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Beilstein-Institut 2018
Materias:	Letter
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6204773/ https://www.ncbi.nlm.nih.gov/pubmed/30410624 http://dx.doi.org/10.3762/bjoc.14.240

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